海峡药学2024，Vol.36Issue(3) ：28-33.

GC-MS/MS联用法测定泉州姜黄中35种农药残留

Determination of 35 Pesticide Residues in Turmeric from Quanzhou by GC-MS/MS

张玲玲 张文州 蔡聪艺 黄幼霞
海峡药学2024，Vol.36Issue(3) ：28-33.
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  • 维普
  • 万方数据

GC-MS/MS联用法测定泉州姜黄中35种农药残留

Determination of 35 Pesticide Residues in Turmeric from Quanzhou by GC-MS/MS

张玲玲 1张文州 1蔡聪艺 1黄幼霞1
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作者信息

  • 1. 泉州医学高等专科学校药学院,福建泉州 362000
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摘要

目的 采用气相色谱-三重四级杆质谱(GC-MS/MS),建立了同时测定泉州本地姜黄中35 种农药残留的分析方法.方法 优化样品前处理,对目标化合物的质谱参数优化,引入环氧七氯B内标法提高实验的稳定性.结果 35 种农药成分在10～500 ng·mL-1 浓度范围内均呈现良好的线性关系,检出限为0.0050～0.0250(mg·kg-1),定量限为0.0125～0.0750(mg·kg-1),样品3 水平添加回收试验的平均回收率范围在84.14%～106.21%,相对标准偏差范围为3.98%～10.57%.结论 该方法可以快速测定姜黄类药材中35 种农药残留量,且简单、灵敏、稳定、准确.

Abstract

OBJECTIVE A method was developed for the simultaneous determination of 35 pesticide residues in Turmeric from Quanzhou by Gas chromatography-triple quadrupole mass spectrometry(GC-MS/MS).METHODS The pretreatment of samples was optimized,the mass spectrum parameters of target compounds were optimized,and the internal standard method of Heptachlor B was introduced to improve the experimental stability.RESULTS The 35 pesticides showed a good linear relationship in the range of 10-500 ng·mL-1.The detection limit was 0.005-0.0250(mg·kg-1),and the quantitative limit was 0.0125-0.0750(mg·kg-1).The average recovery of sample 3 was 84.14%-106.21%,and the RSD was 3.98%-10.57%.CONCLUSION The method was simple,sensitive,stable and accurate for the rapid determination of 35 pesticide residues in Turmeric.

关键词

姜黄/农药残留/气相色谱-三重四级杆质谱/内标

Key words

Turmeric/Pesticide residues/Gas chromatography-triple quadrupole mass spectrometry/Internal standard

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基金项目

泉州市科技计划项目(2021C046R)

出版年

2024
海峡药学
中国药学会福建分会

海峡药学

影响因子：0.643
ISSN：1006-3765
参考文献量12
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