河北农业大学学报2024,Vol.47Issue(5) :101-108.DOI:10.13320/j.cnki.jauh.2024.0074

Co1.5-玉米秸秆生物炭活化过一硫酸盐高效降解莠去津的研究

Efficient degradation of atrazine by Co1.5-Cornstalk biochar activated peroxymonosulfate

段伟迪 张志欣 赵旺 杨冬臣 安泽秀 霍静倩 陈来 张金林
河北农业大学学报2024,Vol.47Issue(5) :101-108.DOI:10.13320/j.cnki.jauh.2024.0074

Co1.5-玉米秸秆生物炭活化过一硫酸盐高效降解莠去津的研究

Efficient degradation of atrazine by Co1.5-Cornstalk biochar activated peroxymonosulfate

段伟迪 1张志欣 1赵旺 1杨冬臣 1安泽秀 1霍静倩 1陈来 1张金林1
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作者信息

  • 1. 河北农业大学植物保护学院,河北保定 071000
  • 折叠

摘要

为解决莠去津的大量使用而导致的环境污染问题,本研究通过水热、煅烧法成功制备出负载型钴基催化剂复合材料Co1.5-玉米秸秆生物炭并构建了过一硫酸盐高效降解体系.通过透射电子显微镜、X射线衍射光谱和比表面积及孔径表征,获得Co1.5-玉米秸秆生物炭催化剂的结构特征信息.对Co1.5-玉米秸秆生物炭/过一硫酸盐体系降解性能和影响因素研究发现,当Co1.5-玉米秸秆生物炭浓度为0.010 g/L、过一硫酸盐浓度为0.075 g/L时,Co1.5-玉米秸秆生物炭/过一硫酸盐体系30 min对莠去津的降解率达到97.96%.本研究为新型高效、绿色催化剂的研发提供了新的制备方案,并为实际废水的治理提供了科学参考.

Abstract

In order to solve the environmental pollution problem caused by the massive use of atrazine,this study successfully prepared a loaded cobalt-based catalyst composite Col.5-Cornstalk biochar and constructed an efficient degradation system of peroxymonosulfate by hydrothermal and calcination method.Information on the structural characteristics of the Co1.5-Cornstalk biochar catalysts was obtained by transmission electron microscopy,X-ray diffraction spectroscopy,and specific surface area and pore size characterization.Further investigation was carried out on the degradation performance of the Col.5-Cornstalk biochar/peroxymonosulfate system and the factors affecting the degradation of atrazine.The degradation rate of Co 1.5-Cornstalk biochar/peroxymonosulfate system for atrazine reached 97.96% in 30 min at the concentration of 0.010 g/L of Co1.5-Cornstalk biochar and 0.075 g/L of peroxymonosulfate.This study provided a new preparation strategy for the research and development of new efficient and green catalysts,and a scientific reference for the treatment of real wastewater.

关键词

莠去津/钴基催化剂/生物炭/过一硫酸盐/OSID

Key words

atrazine/Cobalt-based catalysts/biochar/peroxymonosulfate/OSID

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基金项目

河北省现代农业产业技术体系创新团队(HBCT2024020201)

国家自然科学基金(32272573)

河北省省属高校基本科研业务费研究项目(KY2023062)

河北农业大学引进人才科研专项(YJ2023027)

出版年

2024
河北农业大学学报
河北农业大学

河北农业大学学报

CSTPCD北大核心
影响因子:0.475
ISSN:1000-1573
参考文献量23
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