河北师范大学学报(自然科学版)2025,Vol.49Issue(1) :70-76.DOI:10.13763/j.cnki.jhebnu.nse.202503003

氮掺杂荧光碳点的制备及其对MnO4-的检测

Preparation of Nitrogen-doped Fluorescent Carbon Dots and the Detection Performance for MnO4-

张梓妍 郝运平 李荣慧 方美 耿丽娜
河北师范大学学报(自然科学版)2025,Vol.49Issue(1) :70-76.DOI:10.13763/j.cnki.jhebnu.nse.202503003

氮掺杂荧光碳点的制备及其对MnO4-的检测

Preparation of Nitrogen-doped Fluorescent Carbon Dots and the Detection Performance for MnO4-

张梓妍 1郝运平 1李荣慧 1方美 1耿丽娜1
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作者信息

  • 1. 河北师范大学化学与材料科学学院,石家庄 050024
  • 折叠

摘要

以抗坏血酸和乙二胺为原料,采用一步水热法制备了氮掺杂荧光碳点(N-CDs).利用透射电子显微镜(TEM)、紫外-可见分光光度计(UV-vis)、傅里叶变换红外光谱(FTIR)和荧光光谱对N-CDs进行了表征,并研究了N-CDs对MnO4-的响应机制.结果表明,N-CDs平均粒径为6.41 nm,分散性良好、无明显团聚,荧光量子产率约为15%.N-CDs对MnO4-有较高的选择性和灵敏度,其荧光猝灭程度与MnO4-摩尔浓度(0~60 μmol/L)之间呈良好的线性关系,对MnO4-的检出限为0.055 μmol/L,MnO4-对N-CDs的荧光猝灭机制为动态猝灭.N-CDs可用作荧光传感器,为水中MnO4-的检测提供一种灵敏的新方法.

Abstract

Nitrogen-doped fluorescent carbon dots(N-CDs)were prepared by one-step hydrothermal method using ascorbic acid and ethylenediamine.N-CDs were characterized by transmission electron microscope(TEM),ul-traviolent-visible spectroscopy(UV-vis),Fourier transform infrared(FTIR)and fluorescence spectrum.In ad-dition,the response mechanism of N-CDs to MnO4-was investigated.The results showed that the average particle size of N-CDs was 6.41 nm,the dispersion was good with no obvious agglomeration,and the fluo-rescence quantum yield was about 15%.Experiments indicated that N-CDs had the high selectivity and sen-sitivity to MnO4-,and the fluorescence quenching degree had a good linear relationship with the molar con-centration(0~60 μmol/L)of MnO4-.The detection limit of N-CDs to MnO4-was 0.055 µmol/L,and the fluorescence quenching mechanism of MnO4-on N-CDs was dynamic quenching.N-CDs can be used as fluo-rescence sensor to provide a sensitive method for the detection of MnO4-in water.

关键词

氮元素掺杂/碳点/荧光/MnO4-检测

Key words

nitrogen doping/carbon dots/fluorescence/MnO4-detection

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出版年

2025
河北师范大学学报(自然科学版)
河北师范大学

河北师范大学学报(自然科学版)

影响因子:0.291
ISSN:1000-5854
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