湖北师范大学学报(自然科学版)2024,Vol.44Issue(1) :29-34.DOI:10.3969/j.issn.2096-3149.2024.01.005

Ag/S双掺杂优化Ag2 Te/PEDOT∶PSS热电薄膜性能研究

Optimization of Ag2 Te/PEDOT∶PSS thermoelectric films by Ag/S double doping

张喻 江嘉 卫佳文 汪帅岩 曹文杰 张雄
湖北师范大学学报(自然科学版)2024,Vol.44Issue(1) :29-34.DOI:10.3969/j.issn.2096-3149.2024.01.005

Ag/S双掺杂优化Ag2 Te/PEDOT∶PSS热电薄膜性能研究

Optimization of Ag2 Te/PEDOT∶PSS thermoelectric films by Ag/S double doping

张喻 1江嘉 1卫佳文 1汪帅岩 1曹文杰 1张雄1
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作者信息

  • 1. 湖北师范大学 物理与电子科学学院,湖北 黄石 435002
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摘要

采用湿化学法制备了(Ag2+yS)x@Ag2 Te/PEDOT:PSS,并利用真空抽滤法获得了(Ag2+yS)x@Ag2 Te/PEDOT∶PSS复合薄膜.研究发现 20 MPa冷压下,x = 0.2(y = 0.0)时,复合薄膜(Ag2 S)0.2@Ag2 Te/PE-DOT∶PSS的Seebeck系数绝对值达到最大值-91.13 μV/K,但其电导率仅为7.86 S/cm.为了进一步提高复合薄膜的电导率,在上述基础上调控Ag掺杂量.与y = 0.0 样品相比,y = 0.2 样品的电导率提高到17.89 S/cm(增加了127%),Seebeck系数绝对值略有下降.得益于电导率的大幅度提升,当y = 0.2时样品的功率因子达到最大值11.13 μW/mK2,提高了1.7 倍(与y = 0.0 样品相比),为碲化银基热电薄膜功率因子的提升提供有益参考.

Abstract

In this paper,(Ag2+yS)x@Ag2 Te/PEDOT∶PSS was synthesized by a wet chemical method,and transformed into films by the vacuum filtration method.The results demonstrated that the absolute Seebeck coefficient of(Ag2 S)0.2@Ag2 Te/PEDOT∶PSScomposite films reaches a maximum value of-91.13 μV/K when x =0.2(y =0.0)at 20 MPa cold pressing,but its electric conductivity is only 7.86 S/cm.The Ag doping content was changed to further improve the conductivity of the composite film.Compared with that of the y =0.0 sample,the electric conductivity of the y =0.2 sample increases 127%up to 17.89 S/cm,and the absolute Seebeck coefficient just slightly decreases.Due to the large increase in electric conductivity,the power factor reaches a maximum of 11.13 μW/mK when y =0.2,which is 1.7 times higher than that of the y = 0.0 sample.This study will provide a useful reference for improving the power factor of silver telluride based thermoelectric thin films.

关键词

碲化银/热电性能/热电薄膜/双掺杂

Key words

silver telluride/thermoelectric properties/thermoelectric film/co-doping

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基金项目

湖北省教育厅科学研究计划指导性项目(B2021134)

出版年

2024
湖北师范大学学报(自然科学版)
湖北师范学院

湖北师范大学学报(自然科学版)

影响因子:0.376
ISSN:2096-3149
参考文献量11
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