河北冶金2024,Issue(1) :19-25,37.DOI:10.13630/j.cnki.13-1172.2024.0103

煤种和配比对配合煤热解行为及焦炭孔结构的影响

EFFECTS OF COAL TYPE AND RATIO ON PYROLYSIS BEHAVIOR AND COKE PORE STRUCTURE OF COAL

冯亚威 张鑫 郭瑞 闫国晨 肖强 李彦辉
河北冶金2024,Issue(1) :19-25,37.DOI:10.13630/j.cnki.13-1172.2024.0103

煤种和配比对配合煤热解行为及焦炭孔结构的影响

EFFECTS OF COAL TYPE AND RATIO ON PYROLYSIS BEHAVIOR AND COKE PORE STRUCTURE OF COAL

冯亚威 1张鑫 1郭瑞 1闫国晨 1肖强 1李彦辉1
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作者信息

  • 1. 华北理工大学 化学工程学院,河北唐山 063210
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摘要

随着炼焦煤资源的日益紧张,炼焦工艺对精细配煤的要求越来越高.焦炭的孔结构是影响性能的重要因素,为探究不同炼焦煤对配合煤热解行为和焦炭孔结构的影响,采用吉氏塑性仪、热重分析仪测定了不同配合煤的流动性和热解失重行为.研究发现,不同单种煤的配入对配合煤流动性及挥发分的析出量影响显著,CoalB、CoalE配入量在30%时,配合煤流动度均下降了 48.4 ddpm,CoalC、CoalD配入量在30%时,配合煤流动度分别提升了 902.1 ddpm和520 ddpm.配合煤流动度之间并不具备加和性,而热解挥发分析出量之间具有一定的加和性.利用小型干馏装置,将配合煤进行高温干馏并利用显微图像分析法测试了焦炭的孔结构.研究发现不同的单种煤配入主焦煤后,形成焦炭的平均孔径和平均壁厚与配合煤热解流动特征和挥发分逸出特征有关,但相关性的高低因单种煤的特征而存在差异.不同单种煤对配合煤成焦后平均孔径相关影响系数R2在0.60~0.95之间,不同单种煤对配合煤成焦后平均壁厚相关影响系数R2在0.87~0.95之间.

Abstract

With the increasing shortage of coking coal resources,the coking process has higher and higher requirements for fine coal blending.To explore the influence of different coking coals on the pyrolysis behavior and pore structure of coke coal,the fluidity and pyrolytic weight loss behavior of different coals were measured by Jilds plasticity meter and thermogravimetric analyzer.It is found that the fluidity of coals decreased by 48.4 ddpm when the amount of CoalB and CoalE was 30%,and the fluidity of coals increased by 902.1 ddpm and 520 ddpm when the amount of CoalC and CoalD was 30%,respectively.There is no additivity between the fluidity of the coal,but there is a certain additivity between the output of pyrolysis volatilization.The pore structure of the coke was tested by microscopic image analysis by using a small retort unit to perform high-temperature dry distillation with coal.It is found that the average pore size and average wall thickness of coke formed by different single coal blended with main coking coal are related to the pyrolysis flow characteristics and volatile matter evolution characteristics of the combined coal,but the correlation is different with the characteristics of the single coal.The correlation coefficient R2 of the average pore size of different single coal pairs after coking of the coal is between 0.60~0.95,and the correlation coefficient R2 of the average wall thickness of different single coal pairs is between 0.87~0.95.

关键词

炼焦煤/吉氏流动度/气孔结构/挥发分/焦炭/孔结构

Key words

coking coal/Gildis fluidity/pore structure/volatiles/coke/pore structure

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出版年

2024
河北冶金
河北省冶金学会

河北冶金

影响因子:0.124
ISSN:1006-5008
参考文献量14
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