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高炉渣转炉渣协同处理物相演变

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高炉矿渣和钢渣是钢铁冶炼的主要副产品,不仅产量巨大、处理难度高,而且还会对土壤和环境造成严重破坏,目前综合利用率也较低.为此,研究人员通过在现有钢渣中加入低碱度高炉矿渣进行改质处理,提高钢渣的综合利用率.碱度是影响混合渣物相的主要参数之一,在研究过程中进行了相关分析.采用蔡司高分辨率扫描电子显微镜(SEM)、X射线衍射仪(XRD)和熔点等多种技术手段,对包钢高炉矿渣和钢渣的相组成和形态进行了详尽研究.研究结果显示,随着协同渣系中高炉渣比例不断提高,渣系中的主要含钙相逐渐从硅酸二钙转变为黄长石相,含铁相从铁铝酸钙转变为RO相,含镁相由尖晶石相逐渐转变为蔷薇辉石相和黄长石相,同时含铝相也由尖晶石相转变为黄长石相.说明,低碱度高炉矿渣的加入有助于调整混合渣的物相组成,改善钢渣的性质,进而提高钢渣的综合利用率.该研究可为深入开展高炉矿渣和钢渣的综合利用提供重要的理论和实践参考.
PHYSICAL PHASE EVOLUTION OF BF SLAG AND CONVERTER SLAG COOPERATIVE TREATMENT
Blast furnace slag and steel slag are the main by-products of iron and steel smelting,which not only have huge output and high treatment difficulty,but also cause serious damage to soil and environment.Therefore,researchers improve the comprehensive utilization ratio of steel slag by adding blast furnace slag with low basicity to existing steel slag.Alkalinity is one of the main parameters affecting the phase of mixed slag.The phase composition and morphology of blast furnace slag and steel slag at Baotou Steel were studied by means of Zeiss high resolution Scanning electron microscope(SEM),X-ray diffraction(XRD)and melting point.The results show that with the increase of the proportion of blast furnace slag,the main calcium phase in the slag system changes from dicalcium silicate to feldspar phase,and the iron phase changes from calcium ferric aluminate to RO phase,the magnesium-bearing phase is gradually transformed from spinel phase to rosopyrite phase and feldspar phase,and the aluminum-bearing phase from spinel phase to feldspar phase.It is indicated that the addition of blast furnace slag with low basicity is helpful to adjust the phase composition of mixed slag,improve the properties of steel slag and improve the comprehensive utilization ratio of steel slag.The study can provide important theoretical and practical reference for further comprehensive utilization of blast furnace slag and steel slag.

converter slagblast furnace slagphase evolutionmineral elementsalkalinity

杨爽、张芳

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内蒙古科技大学材料与冶金学院,内蒙古包头 014010

内蒙古自治区先进陶瓷材料与器件重点实验室,内蒙古包头 014010

转炉渣 高炉渣 物相演变 矿相元素 碱度

国家重点研发计划

2020YFC1909105

2024

河北冶金
河北省冶金学会

河北冶金

影响因子:0.124
ISSN:1006-5008
年,卷(期):2024.(3)
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