首页|炼焦煤性质与低阶煤配比对高压型煤成焦性能的影响

炼焦煤性质与低阶煤配比对高压型煤成焦性能的影响

扫码查看
使用低阶煤制备冶金焦炭是缓解炼焦煤资源紧张,优化煤炭资源利用的重要途径.型煤炼焦是高比例使用低阶煤制备冶金焦炭的重要方法.为探究低阶煤在高压型煤炼焦中的应用,研究了焦煤和1/3焦煤添加不同比例低阶煤高压成型高温干馏后型焦的抗压强度、气孔结构、光学组织、表面形貌等方面的特征.结果表明,随着低阶煤配入比例的增加,型焦抗压强度呈先增加后减小的趋势,最高可达到6 kN以上,优于一级冶金球团矿抗压强度2.5 kN的标准.与传统炼焦方式不同,在高压型煤炼焦中,低阶煤与炼焦煤发生交互作用,可以促进焦炭中镶嵌结构的形成,镶嵌结构起到连接焦炭碎裂的组织结构、减少半焦表面孔洞数量和裂缝的作用.添加一定比例的低阶煤可以增加型煤胶质体的透气性,减少高压型煤干馏过程由于挥发分析出受阻而形成的结构缺陷,从而提高型焦的强度.但低阶煤添加比例过高后,会降低型煤胶质体的粘结性,型焦的强度降低.低阶煤的最优配比因炼焦煤的性质而有所不同.在成型压力150 MPa下,低阶煤与主焦煤的最优配比为50%,与1/3焦煤的最优配比为30%.
INFLUENCE OF COKING COAL PROPERTIES AND PROPORTION OF LOW-RANK COAL ON THE COKING PERFORMANCE OF HIGH-PRESSURE BRIQUETTE
The use of low-rank coal to prepare metallurgical coke is an important way to alleviate the shortage of coking coal resources and optimize the utilization of coal resources.Briquette coking is an important method for preparing metallurgical coke from low-rank coal with a high ratio.In order to explore the application of low-rank coal in high-pressure briquette coking,the compressive strength,pore structure,optical structure,surface morphology and other characteristics of coke after high-pressure forming and high-temperature distillation of coking coal and 1/3 coking coal with different ratios of low-rank coal were studied.The results show that with the increase of the ratio of low-rank coal,the compressive strength of briquette coke first increases and then decreases,and the maximum can reach more than 6 kN,exceeding the standard of 2.5 kN for first-class metallurgical pellets.Different from the traditional coking method,in high-pressure briquette coking,the interaction between low-rank coal and coking coal can promote the formation of inlay structure in coke,and the inlay structure plays the role of connecting the microstructure of coke fragmentation and reducing the number of pores and cracks on the surface of colloids.Adding a certain ratio of low-rank coal can increase the gas permeability of briquette colloids,reduce the structural defects formed by the obstruction of volatilization analysis in the high-pressure briquette dry distillation process,and improve the strength of the coke.However,after the ratio of low-rank coal is too high,the adhesion of the colloidal body of the briquette will be reduced,and the strength of the coke will be reduced.The optimal addition ratio of low-grade coal varies depending on the nature of the coking coal.Under the forming pressure of 150 MPa,the optimal matching ratio of low-rank coal to main coking coal is 50%,and the optimal matching ratio with 1/3 coking coal is 30%.

coking coallow rank coalratiobriquette coalcokecompressive strength

李彦辉、郭瑞、廖飞、程欢、胡文佳、肖强

展开 >

华北理工大学化学工程学院,河北唐山 063210

河北省煤化工工程技术研究中心,河北唐山 063210

炼焦煤 低阶煤 配比 型煤 焦炭 抗压强度

国家自然科学基金

U1760111

2024

河北冶金
河北省冶金学会

河北冶金

影响因子:0.124
ISSN:1006-5008
年,卷(期):2024.(9)