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烧结过程一氧化碳减排机理及技术分析

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随着钢铁行业环保形式的日益严峻和人们对环境质量要求的提高,烧结成为我国以长流程工艺为主的钢铁行业中污染物排放最多的工序,在迫切的环境治理面前,有着巨大的减排压力.在烧结其它污染物得到有效治理后,烧结烟气减排CO成为烧结烟气污染物治理的重点.在研究分析烧结烟气CO生成机理的基础上,结合国内外现有烧结减排CO技术,从烧结生产的源头调控、过程控制及末端治理3个方面进行了总结分析.结果表明,源头减排的核心要素是减少燃料配比,通过喷吹含氢介质气体、提高烧结料层厚度等措施降低固体燃料配比;过程控制需要以提升透气性为核心,寻求合理协同技术,提高燃料的燃烧程度,例如通过喷吹蒸汽、富氧燃烧、优化燃料粒度等措施提升CO向CO2的转化率;末端治理则需要探索适用于烧结复杂烟气条件下的CO转化吸收技术,寻求抗水、抗S能力强且价格低廉的催化剂等.
MECHANISM AND TECHNICAL ANALYSIS OF CARBON MONOXIDE EMISSION REDUCTION IN SINTERING PEOCESS
As the environmental protection form of steel industry is severe and people's requirements for environmental quality are improved,sintering has become the most polluting process in Chinas iron and steel industry,which is dominated by long-process technology.In the face of urgent environmental control,there is a huge pressure to reduce emissions.After other sintering pollutants are effectively treated,the emission reduction of sintering flue gas CO has become the focus of sintering flue gas pollutant treatment.Based on the research and analysis of the mechanism of CO generation in sintering flue gas,combined with the existing sintering emission reduction technologies at home and abroad,this paper summarized and analyzed the source control,process control and end treatment of sintering production.The results show that the core element of source emission reduction is to reduce the fuel ratio,and to reduce the solid fuel ratio by injecting hydrogen-containing medium gas and increasing the thickness of sintering bed.The process control needs to consider the dynamic control factors that affect the combustion reaction of fuel to improve the combustion degree of fuel,and the conversion rate of CO to CO2 can be improved by steam injection,oxygen-enriched combustion and fuel particle size optimization.At the end of the treatment,it is necessary to explore the CO conversion and absorption technology suitable for sintering complex flue gas conditions,and to seek water-resistant,S-resistant and low-cost catalysts.

sintering flue gasCOcombustion mechanismemission reduction technologyenergy saving and consumption reduction

佘雪峰、钟庭梁、王延江、孟延军、王静松

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北京科技大学钢铁冶金新技术国家重点实验室,北京 100083

德龙钢铁有限公司烧结厂,河北邢台 054009

烧结烟气 CO 燃烧机理 减排技术 节能降耗

2024

河北冶金
河北省冶金学会

河北冶金

影响因子:0.124
ISSN:1006-5008
年,卷(期):2024.(10)