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硅橡胶-聚丙烯酸酯微球增韧聚乳酸研究

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为了改善聚乳酸的韧性,将硅橡胶-聚甲基丙烯酸甲酯粒子和聚乳酸通过熔融共混制备聚乳酸共混物,研究了硅橡胶-聚甲基丙烯酸甲酯粒子交联度、核壳比以及含量对于聚乳酸力学性能的影响。结果表明,当交联剂KH570用量为8%,核壳质量比为7:3时,聚乳酸共混物的抗冲击强度为2。88kJ/m2,拉伸强度为51。08MPa,增韧效果最佳;当硅丙粒子含量从0增加至18%时,PLA的抗冲击强度从1。37kJ/m2增加至8。67kJ/m2,增加了 5。33倍;拉伸强度从74。77MPa下降至38。86MPa;断裂伸长率从2。08%增加至25。45%;弯曲强度从106。64MPa下降至72。74MPa。
Study on Toughening Polylactic Acid by Silicone Rubber-Polyacrylate Microspheres
In order to improve the toughness of polylactic acid(PLA),PLA blend was prepared by melting blend of silicone rubber-poly(methyl methacrylate)particles and polylactic acid.The effects of cross-linking degree,core-shell ratio and content of silicone rubber-poly(methyl methacrylate)particles on the mechanical properties of PLA were studied.The results showed that the impact strength and tensile strength of polylactic acid blend were 2.88 kJ/m2 and 51.08 MPa respectively when the amount of crosslinker KH570 was 8%and the core-shell mass ratio was 7:3.The impact strength of PLA increased 5.33 times from 1.37 kJ/m2 to 8.67 kJ/m2 when the content of silicon-C particles increased from 0 to 18%.Tensile strength decreased from 74.77 MPa to 38.86 MPa;Elongation at break increased from 2.08%to 25.45%;The bending strength decreased from 106.64MPa to 72.74 MPa.

silicone rubber-polymethyl methacrylatepolylactic acidtoughening

刘美意、张镇鹏、马凤国

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青岛科技大学橡塑材料与工程教育部重点实验室/山东省橡塑材料与工程重点实验室,山东青岛 266042

硅橡胶-聚甲基丙烯酸甲酯 聚乳酸 增韧

2024

合成材料老化与应用
广州合成材料研究院

合成材料老化与应用

CSTPCD
影响因子:0.279
ISSN:1671-5381
年,卷(期):2024.53(3)