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液滴微流控技术制备纳米聚合物微球及性能评价

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以改性聚丙烯酰胺作为分散相单体,3#白油和十二烷基硫酸钠(SDS)作为连续相,通过液滴微流控技术制备出一种纳米聚合物微球PQM-1。优化了 PQM-1的制备条件,并评价了其吸附性能。结果表明:随着单体浓度和交联剂用量的逐渐增大,PQM-1的膨胀倍数逐渐减小;随着引发剂用量的逐渐增大,PQM-1的膨胀倍数逐渐增大。推荐最佳的单体浓度为25%,最佳的交联剂的用量为3%,最佳的引发剂的用量为3%。当亚甲基蓝溶液浓度为50mg/L,吸附时间为2h时,PQM-1对亚甲基蓝的吸附效率可以达到98。7%,吸附性能较好。
Preparation and Performance Evaluation of Nano Polymer Microspheres Using Droplet Microfluidic Technology
A nano polymer microsphere PQM-1 was prepared by droplet microfluidic technology using modified polyacrylamide as the dispersed monomer,3# white oil and sodium dodecyl sulfate(SDS)as the continuous phase.The preparation conditions of PQM-1 were optimized and its adsorption performance was evaluated.The results showed that as the monomer concentration and crosslinking agent dosage gradually increased,the expansion ratio of PQM-1 gradually decreased;As the amount of initiator gradually increased,the expansion factor of PQM-1 gradually increased.The recommended optimal monomer concentration is 25%,the optimal crosslinking agent dosage is 3%,and the optimal initiator dosage is 3%.When the concentration of methylene blue solution is 50 mg/L and the adsorption time is 2 hours,the adsorption efficiency of PQM-1 for methylene blue can reach 98.7%,indicating good adsorption performance.

microfluidic technologypolymer microspheresexpansion performanceadsorption performancemethylene blue

雷蕾、刘聪、张森

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徐州工程学院土木工程学院,江苏徐州 221000

中国矿业大学徐海学院,江苏徐州 221000

中国铁路上海局集团有限公司合肥车辆段,安徽合肥 230012

微流控技术 聚合物微球 膨胀性能 吸附性能 亚甲基蓝

江苏省自然科学基金江苏高校哲学社会科学研究一般项目

BK202001732022SJYB1194

2024

合成材料老化与应用
广州合成材料研究院

合成材料老化与应用

CSTPCD
影响因子:0.279
ISSN:1671-5381
年,卷(期):2024.53(4)
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