首页|二氧化硅含量对亚光聚酯薄膜性能影响研究

二氧化硅含量对亚光聚酯薄膜性能影响研究

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采用超有光聚酯和亚光聚酯,经过共混、熔融挤出、双向拉伸等方式制备了不同二氧化硅含量的亚光薄膜,采用差示扫描量热仪(DSC)研究了不同样品厚片的热性能,计算了相应的结晶性能参数;利用双向拉伸试验机在亚光薄膜制备过程中对比了不同样品拉伸过程中的拉力-拉伸倍率曲线;采用透射雾度仪、激光共聚焦显微镜等仪器分析了不同二氧化硅含量亚光薄膜的光学性能、微观形貌和表面粗糙度.结果表明,随着二氧化硅含量的增加,相应亚光聚酯样品的Tc 逐渐降低,熔融结晶Avrami指数n呈现升高趋势,半结晶期t1/2 则呈现降低的趋势.随着亚光聚酯样品中二氧化硅含量的增加,相同加工条件下其拉力呈现上升的趋势,而且拉伸倍率越高差异越大.二氧化硅含量对于亚光薄膜的光泽度影响最大,雾度影响次之,透过率影响最小;二氧化硅会引起薄膜粗糙度发生较大的变化,随着二氧化硅含量的增加,粗糙度先增大后减小,然后趋于稳定,薄膜表面趋于平整化.征化纤有限责任公司;膜级亚光聚酯,FG613,工业级,中国石化仪征化纤有限责任公司.
Effect of silica content on properties of matte polyester films
By using melting extrusion,bidirectional stretching,and blending,matte films with varying sili-ca contents were created.Using a differential scanning calorimeter(DSC),the thermal characteristics of the matte samples were examined,and the crystallization properties were computed.The biaxial tensile testing ma-chine compared the stress-strain curves of various samples during the matte film preparation process.Use of a la-ser confocal microscope and transmission fog meter allowed for the analysis of the surface roughness,morphology,and optical characteristics of matte films with varying silica contents.The results show that on the sur-face,the Tc of matte polyester samples gradually dropped,the Avrami index n of melt crystallization increased,and the half crystallization period t1/2 decreased as the silica content increased.Under the same processing conditions,the tensile stress of matte polyester samples increased as the silica content increased.The greater the difference,the higher the tensile ratio.The degree of fog has the second-biggest impact on matte film gloss,while transmit-tance has the least impact.The content of dioxide has the biggest impact.Excessive micron powder will flatten the film's surface,and silica will alter the film's essential roughness.

PETsilicamatte filmprocessabilityservice performance

郭颖、司虎、王新华、王树霞

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中国石化仪征化纤有限责任公司,江苏仪征 211900

江苏省高性能纤维重点实验室,江苏仪征 211900

聚对苯二甲酸乙二醇酯 二氧化硅 亚光薄膜 加工性能 使用性能

2024

合成技术及应用
中国石化仪征化纤股份有限公司

合成技术及应用

影响因子:0.204
ISSN:1006-334X
年,卷(期):2024.39(1)
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