首页|CHDM含量对PETG共聚酯性能的影响

CHDM含量对PETG共聚酯性能的影响

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通过共聚法制备了不同 1,4-环己烷二甲醇(CHDM)含量的聚对苯二甲酸乙二醇-1,4-环己烷二甲醇酯(PETG).通过旋转流变仪、差示扫描量热仪及万能试验机等研究了CHDM含量对共聚酯流变性能、热性能及力学性能的影响.结果表明,随CHDM含量的增加,相同温度下的PETG共聚酯动力黏度增加,结晶能力下降,当CHDM含量达到20%时,共聚物由结晶聚合物转变为非晶聚合物.随着CHDM含量的增加,PETG共聚酯的拉伸强度增加而弹性模量和断裂伸长率下降,透光率增加而雾度下降.
The effect of CHDM content on the properties of PETG copolyester
Using the copolymerization process,polyethylene terephthalate-1,4-cyclohexanediol ester(PETG)was created with varying concentrations of 1,4-cyclohexanedimethanol(CHDM)content.The impact of CHDM concentration on the rheological,thermal,and mechanical characteristics of copolyesters was investigated through the use of a universal testing machine,differential scanning calorimeter,and rotary rheometer.The find-ings demonstrated that while PETG's ability to crystallize reduced,dynamic viscosity at the same temperature in-creased as CHDM content increased.The copolymer changed from crystalline polymer to amorphous polymer when the CHDM content reached 20%.The tensile strength of PETG copolyester increases as the CHDM content increa-ses,whereas the transmittance increases,the haze decreases,and the elastic modulus and elongation at break de-crease.

polyethylene terephthalate-1,4-cyclohexanediol ester1,4-cyclohexanedimethanolrheological propertiesthermal propertiesmechanical properties

石雪龙、王余伟、夏峰伟

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中国石化仪征化纤有限责任公司研究院,江苏仪征 211900

聚对苯二甲酸乙二醇-1,4-环己烷二甲醇酯 1,4-环己烷二甲醇 流变性能 热性能 力学性能

2024

合成技术及应用
中国石化仪征化纤股份有限公司

合成技术及应用

影响因子:0.204
ISSN:1006-334X
年,卷(期):2024.39(1)
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