合成润滑材料2024,Vol.51Issue(3) :12-16.DOI:10.3969/j.issn.1672-4364.2024.03.003

差示扫描量热法测定压缩机油-引发剂混合体系半衰期

Determination of Half-Life of Compressor Oil-Initiator Mixed Systems by Differential Scanning Calorimetry

李琰 曹凯 陆海 吴旭东 王荣
合成润滑材料2024,Vol.51Issue(3) :12-16.DOI:10.3969/j.issn.1672-4364.2024.03.003

差示扫描量热法测定压缩机油-引发剂混合体系半衰期

Determination of Half-Life of Compressor Oil-Initiator Mixed Systems by Differential Scanning Calorimetry

李琰 1曹凯 1陆海 1吴旭东 1王荣2
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作者信息

  • 1. 中国石化润滑油有限公司合成油脂分公司,重庆 400039
  • 2. 德国耐驰仪器制造有限公司,上海 200000
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摘要

采用差示扫描量热法(DSC)和Kinetics Neo专业软件建立了相应的化学动力学模型,对超高压乙烯压缩机油-引发剂混合体系的半衰期进行了研究.建立的3步连串模型适用于压缩机油-引发剂混合体系半衰期的测定.测定结果表明,国产压缩机油+DTBP引发剂混合体系和进口压缩机油+DTBP引发剂混合体系对DTBP引发剂半衰期的影响均较小,国产压缩机油和进口压缩机油与乙烯反应介质的相容性相当.(图11表2参考文献9)

Abstract

A corresponding chemical kinetics model was established using Differential Scanning Calorimetry(DSC)and Kinetics Neo software to study the half-life of the ultrahigh pressure ethylene compressor oil-initiator mixed system.The established three-step sequential model is suitable for determining the half-life of the compressor oil-initiator mixed system.The results show that the influence of the domestic compressor oil+DTBP initiator mixed system and the imported compressor oil+DTBP initiator mixed system on the half-life of the DTBP initiator is minimal,and the compatibility of domestic compressor oil and imported compressor oil with ethylene reaction medium is comparable.(Charts11 Tables2 References9)

关键词

氧化诱导期/活化能/化学动力学模型/相容性

Key words

oxidation induction period/activation energy/chemical kinetics model/compatibility

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出版年

2024
合成润滑材料
中国石化股份公司润滑油分公司

合成润滑材料

影响因子:0.302
ISSN:1672-4364
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