合成树脂及塑料2024,Vol.41Issue(2) :16-20,29.DOI:10.19825/j.issn.1002-1396.2024.02.04

脲醛树脂包覆的环氧树脂微胶囊对树脂自修复性能的影响

Effect of urea-formaldehyde resin-coated epoxy resin microcapsules on self-healing properties of resin

陈毅 刘景勃 张发爱
合成树脂及塑料2024,Vol.41Issue(2) :16-20,29.DOI:10.19825/j.issn.1002-1396.2024.02.04

脲醛树脂包覆的环氧树脂微胶囊对树脂自修复性能的影响

Effect of urea-formaldehyde resin-coated epoxy resin microcapsules on self-healing properties of resin

陈毅 1刘景勃 1张发爱1
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作者信息

  • 1. 桂林理工大学材料科学与工程学院,广西桂林 541004
  • 折叠

摘要

将自制脲醛树脂包覆的环氧树脂微胶囊添加到环氧树脂基体中,制备了环氧树脂自修复复合材料.采用锥形双悬臂梁法分析了环氧树脂微胶囊的粒径、用量、制备方法对环氧树脂/环氧树脂微胶囊复合材料自修复效率的影响,观察了其自修复过程,揭示了自修复机理.结果表明:采用二步法制备的微胶囊,在微胶囊粒径为97~150 μm,用量为15%(w)时,复合材料的自修复效率达到最大,为104.7%.

Abstract

The self-healing epoxy resin composites were prepared by adding homemade urea-formaldehyde resin-coated epoxy ethyl acetate microcapsules to the epoxy resin matrix.The effects of particle size,dosage and preparation method of the epoxy resin microcapsules on the self-healing efficiency of the epoxy resin/epoxy microcapsules were tested by the conical double cantilever beam method to observe the self-healing process and reveal the self-healing mechanism.The results show that the self-healing efficiency of the composites reaches the maximum of 104.7%when the microcapsule particle size is 97-150 μm and the mass fraction of the microcapsules is 15%prepared by the two-step method.

关键词

脲醛树脂/环氧树脂/微胶囊/复合材料/自修复性能/制备工艺

Key words

urea-formaldehyde resin/epoxy resin/microcapsule/composite material/self-healing property/preparation process

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基金项目

国家自然科学基金(51263004)

出版年

2024
合成树脂及塑料
中国石化集团资产经营管理有限公司北京燕山石化分公司 橡塑新型材料合成国家工程研究中心

合成树脂及塑料

CSTPCD北大核心
影响因子:0.384
ISSN:1002-1396
参考文献量16
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