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乙烯与1-己烯共聚合及其共聚物研究

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在1L聚合釜中进行乙烯与1-己烯共聚合,研究了乙烯与1-己烯共聚合的动力学、竞聚率及所制共聚物的结构与性能,并模拟了串联和并联工艺.结果表明:1-己烯的共聚合能力较好,且具有较好的氢调敏感性,共聚合过程平稳,共聚物颗粒形态较好;乙烯-1-己烯共聚物与参比试样物性基本相当,熔融焓、结晶焓和1-己烯含量略高.
Copolymerization of ethylene and 1-hexene and its copolymers
The copolymerization of ethylene and 1-hexene was carried out in a 1 L polymerization reactor,whose kinetics and reactivity ratio,structure and properties of the copolymer were studied.The series and parallel processes were simulated.The results show that 1-hexene performs excellently in copolymerization ability and hydrogen modulation sensitivity with a stable copolymerization process and copolymer particle morphology.The physical properties of ethylene-1-hexene copolymer are basically equivalent to those of the reference sample,while its melting enthalpy,crystallization enthalpy,and 1-hexene content are slightly higher.

ethylene1-hexenecopolymerizationhydrogen sensitivityparticle morphology

甄建

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北京燕山石化高科技术有限责任公司,北京 102500

乙烯 1-己烯 共聚合 氢调敏感性 颗粒形态

2024

合成树脂及塑料
中国石化集团资产经营管理有限公司北京燕山石化分公司 橡塑新型材料合成国家工程研究中心

合成树脂及塑料

CSTPCD北大核心
影响因子:0.384
ISSN:1002-1396
年,卷(期):2024.41(3)
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