首页|国产第五代非邻催化剂在Unipol工艺聚丙烯装置上的工业应用

国产第五代非邻催化剂在Unipol工艺聚丙烯装置上的工业应用

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介绍了国产第五代非邻苯二甲酸酯内给电子体催化剂(简称非邻催化剂)SUG-H在400 kt/a Unipol工艺聚丙烯装置上的工业应用情况,考察了SUG-H型催化剂的聚合适应性及其产品性能.结果表明:由于SUG-H型催化剂使用非邻苯二甲酸酯内给电子体和特殊的制备工艺,因此组成、形貌、粒径及其分布与参比催化剂相差较大;使用SUG-H型催化剂时,装置运行平稳,催化剂的氢调敏感性好,活性高;聚丙烯粉料堆密度适中,粒径分布窄,粒子形态好且细粉含量低,特别适合用于Unipol工艺聚丙烯装置.
Application of homemade 5th generation non-PAEs catalyst in Unipol PP process
Application of the domestic 5th generation non-phthalic acid ester(PAEs)catalyst,SUG-H,in a 400 kt/a Unipol polypropylene process was introduced.The adaptability of SUG-H catalyst and product properties it produces were evaluated.The results show that due to the non-PAEs internal donor and special production method,the composition,morphology,particle size and distribution of SUG-H catalyst are quite different from those of the reference catalyst.The unit operates stable when SUG-H catalyst is applied,and the catalyst has good hydrogen response and high activity.The polymer powder has a medium bulk density,narrow particle size distribution,good morphology and very low fines,which is perfect for Unipol PP process.

Unipol processpolypropylenenon-phthalic acid ester catalystindustrial applicationcatalyst activitymechanical property

王耀华、喻秉俊、张军伟、程林杰、达杰、林永生

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东华能源(宁波)新材料有限公司,浙江宁波 315042

北京利和知信科技有限公司,北京 100050

Unipol工艺 聚丙烯 非邻苯二甲酸酯内给电子体催化剂 工业应用 催化剂活性 力学性能

2024

合成树脂及塑料
中国石化集团资产经营管理有限公司北京燕山石化分公司 橡塑新型材料合成国家工程研究中心

合成树脂及塑料

CSTPCD北大核心
影响因子:0.384
ISSN:1002-1396
年,卷(期):2024.41(5)