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国内外交联聚乙烯绝缘料用聚乙烯性能对比

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研究了国内外3种交联聚乙烯绝缘料用聚乙烯的基本物性、结构与性能之间的差异.结果表明:进口料的熔体流动速率较高,拉伸性能更好,重均分子量高,相对分子质量分布较窄,支化度和熔体强度低,端基双键含量高,但总双键含量与国产料接近.与进口料相比,国产料具有较高的熔融温度,较低的结晶温度.2种国产料交联性能有一定差别,其中一种国产料的平衡扭矩最大,交联时间短,估计与其支化度高,交联后缠结更充分有关.
Comparison of properties of polyethylene used for XLPE insulation materials at home and abroad
The differences of three kinds of cross-linked polyethylene insulation materials at home and abroad in basic physical properties and structural properties were studied.The results show that the imported material has higher melt flow rate,better tensile properties,higher weight average molecular weight,narrower relative molecular weight distribution,lower branching degree and melt strength,and higher terminal double bond content,but its total double bond content is close to that of the domestic material.The domestic materials have higher melting temperature and lower crystallization temperature than those of imported resin.There are some differences in crosslinking properties between the two domestic materials.One domestic material has the largest equilibrium torque and short crosslinking time,which is estimated to be related to its high branching degree and more sufficient entanglement after crosslinking.

polyethylenecross-linkingcable insulantcrystallization temperaturemelting temperature

魏福庆、邸麟婷、许惠芳、秦晨元、王梓丞

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中国石油天然气股份有限公司兰州化工研究中心,甘肃 兰州 730060

聚乙烯 交联 电缆绝缘料 结晶温度 熔融温度

2024

合成树脂及塑料
中国石化集团资产经营管理有限公司北京燕山石化分公司 橡塑新型材料合成国家工程研究中心

合成树脂及塑料

CSTPCD北大核心
影响因子:0.384
ISSN:1002-1396
年,卷(期):2024.41(6)