合成橡胶工业2024,Vol.47Issue(2) :115-121.DOI:10.19908/j.cnki.ISSN1000-1255.2024.02.0115

环氧化杜仲胶湿法接枝二氧化硅的制备与性能

Preparation and properties of epoxidized Eucommia ulmoides gum grafted with silicon dioxide by wet method

应月 杨凤 李龙 方庆红
合成橡胶工业2024,Vol.47Issue(2) :115-121.DOI:10.19908/j.cnki.ISSN1000-1255.2024.02.0115

环氧化杜仲胶湿法接枝二氧化硅的制备与性能

Preparation and properties of epoxidized Eucommia ulmoides gum grafted with silicon dioxide by wet method

应月 1杨凤 1李龙 1方庆红1
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作者信息

  • 1. 沈阳化工大学材料科学与工程学院/辽宁省橡胶弹性体重点实验室,沈阳 110142
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摘要

首先对杜仲胶(EUG)进行环氧化改性得到环氧化EUG(EEUG),然后对EEUG进行湿法接枝二氧化硅(SiO2)制备出EEUG接枝SiO2复合材料(EEUG-g-SiO2),研究了EEUG-g-SiO2复合材料的结构与性能.结果表明,相较于机械共混物EUG/SiO2和EEUG/SiO2,EEUG-g-SiO2硫化胶中纳米SiO2的分散性改善明显,力学性能大幅度提升;与EUG/SiO2硫化胶相比,EEUG-g-SiO2硫化胶的撕裂强度提高了30.9%,耐疲劳性能提升了575.0%,磨耗量降低了94%;与EEUG/SiO2硫化胶相比,EEUG-g-SiO2硫化胶的撕裂强度提高了10.5%,耐疲劳性能提升了68.6%,磨耗量降低了72%,压缩生热明显降低.

Abstract

Firstly,Eucommia ulmoides gum(EUG)was epoxidized to obtain epoxidized EUG(EEUG).Then,EEUG grafted silicon dioxide(SiO2)composite(EEUG-g-SiC2)was prepared by wet graf-ting SiO2 onto EEUG.The structure and properties of EEUG-g-SiC2 composite were studied.The results showed that compared with EUG/SiO2 and EEUG/SiO2 mechanical blends,the dispersion of nano SiO2 in EEUG-g-SiO2 vulcanizate was significantly improved and the mechanical properties were greatly improved.Compared with EUG/SiO2 vulcanizates,the tear strength of EEUG-g-SiO2 vulcanizate in-creased by 30.9%,fatigue resistance increased by 575%,and abrasion decreased by 94%.Compared with EEUG/SiO2 vulcanizate,the tear strength of EEUG-g-SiO2 vulcanizate increased by 10.5%,fatigue resistance increased by 68.6%,abrasion decreased by 72%,and the compression heat build-up decreased significantly.

关键词

环氧化杜仲胶/二氧化硅/接枝/结晶性能/硫化特性/物理机械性能/压缩生热/耐疲劳性能

Key words

epoxidized Eucommia ulmoides gum/silicon dioxide/graft/crystallinity/curing cha-racteristics/physical and mechanical property/com-pression heat build-up/fatigue resistance

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基金项目

中国科学院战略性先导科技专项子课题(XDC 06010206)

出版年

2024
合成橡胶工业
中国石油天然气股份有限公司兰州石化分公司

合成橡胶工业

CSTPCD
影响因子:0.401
ISSN:1000-1255
参考文献量22
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