合成橡胶工业2024,Vol.47Issue(2) :153-159.DOI:10.19908/j.cnki.ISSN1000-1255.2024.02.0153

减振制品用天然橡胶在存储过程中结构与性能的演变

Evolution of structure and properties of natural rubber for vibration damping products during storage

刘治澳 赵庆镇 马春临 李培军
合成橡胶工业2024,Vol.47Issue(2) :153-159.DOI:10.19908/j.cnki.ISSN1000-1255.2024.02.0153

减振制品用天然橡胶在存储过程中结构与性能的演变

Evolution of structure and properties of natural rubber for vibration damping products during storage

刘治澳 1赵庆镇 1马春临 1李培军1
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作者信息

  • 1. 青岛科技大学高分子科学与工程学院/橡塑材料与工程教育部重点实验室,山东青岛 266042
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摘要

采用长期储存和加速老化相结合的方法对减振制品用天然橡胶(NR)在存储过程中结构与性能的演变进行研究.结果表明,随着老化温度的升高和老化时间的延长,NR硫化胶的硬度、100%定伸应力、300%定伸应力、储能模量和损耗模量均逐渐增大且总体变化趋势与交联密度的变化趋势相近,拉伸强度和扯断伸长率的变化率均呈现整体下降趋势,而损耗因子则迅速降低并趋于稳定,动静刚度比呈现先降低后缓慢上升的趋势;热空气老化对NR硫化胶减振性能的影响较小.

Abstract

The evolution of structure and proper-ties of natural rubber(NR)for vibration damping products during storage was studied by long-term storage method and accelerated aging method.The results showed that the hardness,modulus at 100%,modulus at 300%,storage modulus and loss modulus of NR vulcanizates increased gradually with increase of aging temperature and aging time,and the overall change trend was similar to that of crosslinking den-sity.The change rates of tensile strength and elonga-tion at break decreased while the loss factor decreased rapidly and tended to be stable.The ratio of dynamic stiffness and static stiffness decreased first and then increased slowly.Hot air aging had little effect on the vibration reduction performance of NR vulcanizates.

关键词

天然橡胶/空气弹簧/热氧老化/交联密度/硬度/动态力学性能/动静刚度比

Key words

natural rubber/air spring/thermal-oxidative aging/crosslinking density/hardness/dy-namic mechanical property/ratio of dynamic stiffness and static stiffness

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基金项目

国家重点研究计划项目(2108 YFC 1902600)

出版年

2024
合成橡胶工业
中国石油天然气股份有限公司兰州石化分公司

合成橡胶工业

CSTPCD
影响因子:0.401
ISSN:1000-1255
参考文献量16
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