合成橡胶工业2024,Vol.47Issue(5) :416-420.DOI:10.19908/j.cnki.ISSN1000-1255.2024.05.0416

撕裂模式下乙烯-丙烯酸甲酯共聚物/氯丁橡胶热塑性硫化胶的Mullins效应及其可逆回复

Mullins effect and its reversible recovery of ethylene-methyl acrylate copolymer/chloroprene rubber thermoplastic vulcanizate under tearing mode

朱大志 张卫然 高原 王兆波
合成橡胶工业2024,Vol.47Issue(5) :416-420.DOI:10.19908/j.cnki.ISSN1000-1255.2024.05.0416

撕裂模式下乙烯-丙烯酸甲酯共聚物/氯丁橡胶热塑性硫化胶的Mullins效应及其可逆回复

Mullins effect and its reversible recovery of ethylene-methyl acrylate copolymer/chloroprene rubber thermoplastic vulcanizate under tearing mode

朱大志 1张卫然 1高原 1王兆波1
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作者信息

  • 1. 青岛科技大学材料科学与工程学院,山东青岛 266042
  • 折叠

摘要

采用动态硫化法制备出乙烯-丙烯酸甲酯共聚物(EMA)/氯丁橡胶(CR)热塑性硫化胶(TPV),考察了不同m(EMA)/m(CR)时TPV的撕裂强度,研究了撕裂模式下TPV的Mullins效应及其热处理下的可逆回复行为.结果表明,当m(EMA)/m(CR)为40/60时EMA/CR TPV的撕裂强度最高;在单轴循环撕裂模式下EMA/CR TPV存在明显的Mullins效应,当应变速率增大时EMA/CR TPV的最大撕裂强度、内耗和阻尼因子均呈增大趋势;当撕裂应变增大时EMA/CR TPV的最大撕裂强度、瞬时残余形变、内耗和阻尼因子均呈增大趋势,但应力软化因子呈减小趋势.热处理后EMA/CR TPV的Mullins效应的可逆回复能力增强,并且在80 ℃时的可逆回复效果达到最佳.

Abstract

Ethylene-methyl acrylate copolymer(EMA)/chloroprene rubber(CR)thermoplastic vul-canizate(TPV)was prepared by dynamic vulcaniza-tion and tear strength with different m(EMA)/m(CR)was investigated.The Mullins effect of TPV under tear mode and reversible behavior under heat treat-ment were studied.The results showed that tear strength of EMA/CR TPV was the highest when m(EMA)/m(CR)was 40/60.There was obvious Mullins effect in EMA/CR TPV under uniaxial cyclic tearing mode,and when the strain rate increased,the maximum tear strength,internal friction and damping factor of EMA/CR TPV all increased.When the tear strain increased,the maximum tear strength,instan-taneous residual deformation,internal friction and damping factor of EMA/CR TPV all increased,but the stress softening factor decreased.The reversible recovery ability of Mullins effect of EMA/CR TPV was enhanced after heat treatment,and the reversible recovery effect was the best at 80 ℃.

关键词

乙烯-丙烯酸甲酯共聚物/氯丁橡胶/动态硫化/Mullins效应/撕裂模式/可逆回复

Key words

ethylene-methyl acrylate copolymer/chloroprene rubber/dynamic vulcanization/Mullins effect/tearing mode/reversibility

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基金项目

山东省自然科学基金资助项目(ZR 2021 ME028)

出版年

2024
合成橡胶工业
中国石油天然气股份有限公司兰州石化分公司

合成橡胶工业

CSTPCD
影响因子:0.401
ISSN:1000-1255
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