合成橡胶工业2024,Vol.47Issue(5) :421-427.DOI:10.19908/j.cnki.ISSN1000-1255.2024.05.0421

低温等离子体活化氯丁橡胶和乙烯-乙酸乙烯酯共聚物及其复配改性沥青的性能

Low-temperature plasma activated chloroprene rubber and ethylene-vinyl acetate copolymer and their compound modified asphalt performance

田永静 王宇航 茆一鸣
合成橡胶工业2024,Vol.47Issue(5) :421-427.DOI:10.19908/j.cnki.ISSN1000-1255.2024.05.0421

低温等离子体活化氯丁橡胶和乙烯-乙酸乙烯酯共聚物及其复配改性沥青的性能

Low-temperature plasma activated chloroprene rubber and ethylene-vinyl acetate copolymer and their compound modified asphalt performance

田永静 1王宇航 1茆一鸣2
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作者信息

  • 1. 苏州科技大学环境科学与工程学院,江苏苏州 215009
  • 2. 苏州科技大学环境科学与工程学院,江苏苏州 215009;苏州科技大学江苏省生态道路技术产业化工程研究中心,江苏苏州 215009;苏州市建设工程质量检测中心有限公司,江苏苏州 215000
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摘要

为提升胶粉改性沥青的性能,以与基质沥青质量比为11/100的氯丁橡胶(CR)和3/100的乙烯-乙酸乙烯酯共聚物(EVA)为改性剂制备了改性沥青,采用低温等离子体活化CR/EVA以进一步提升复配改性沥青的性能,研究了单一改性、复配改性和低温等离子体活化复配改性沥青(A-CR/EVA-MA)的路用性能,并使用扫描电子显微镜、原子力显微镜和傅里叶变换红外光谱分析了各改性沥青的微观机理.结果表明,各改性沥青的路用性能均有提升,总体表现为活化复配改性优于复配改性和单一改性;A-CR/EVA-MA的针入度、软化点、延度、布氏黏度及抗车辙因子较基质沥青分别提升了 46%、47%、95%、253%和278%,存储稳定性也得到了进一步提高;低温等离子体活化技术增加了改性剂的比表面积和表面官能团含量,提高了改性剂对沥青中轻质组分的吸附能力,促进了 CR和EVA与沥青的紧密结合,有效提升了改性沥青的路用性能.

Abstract

In order to improve the performance of crumb rubber modified asphalt,chloroprene rubber(CR)with a mass ratio of 11/100 to matrix asphalt and ethylene-vinyl acetate copolymer(EVA)with a mass ratio of 3/100 were used as modifiers to prepare modified asphalt.CR/EVA was activated by low-temperature plasma to further improve the perfor-mance of compound modified asphalt.The road per-formance of single modified,compound modified and low-temperature plasma activated compound modi-fied asphalt(A-CR/EVA-MA)were studied.The mi-croscopic mechanism of each modified asphalt was analyzed by scanning electron microscopy,atomic force microscopy and Fourier transform infrared spectroscopy.The results showed that the road per-formance of each modified asphalt was improved,and the overall performance of the activation modifi-cation system was better than those of compound modification and the single modification system.The penetration,softening point,ductility,Brookfield viscosity and anti-rutting factor of A-CR/EVA-MA increased by 46%,47%,94%,253%,and 278%re-spectively compared to the matrix asphalt,and the storage stability was also further improved.The low-temperature plasma activation technology increased the specific surface area and surface functional group content of the modifier,improved the adsorp-tion capacity of the modifier to the light components in the asphalt,promoted the close combination of CR,EVA and asphalt,and improved effectively the road performance of the modified asphalt.

关键词

改性沥青/低温等离子体/氯丁橡胶/乙烯-乙酸乙烯酯共聚物/路用性能/微观机理

Key words

modified asphalt/low-temperature plasma/chloroprene rubber/ethylene-vinyl acetate copolymer/road performance/microscopic mecha-nism

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基金项目

国家自然科学基金资助项目(51378328)

出版年

2024
合成橡胶工业
中国石油天然气股份有限公司兰州石化分公司

合成橡胶工业

CSTPCD
影响因子:0.401
ISSN:1000-1255
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