合成橡胶工业2024,Vol.47Issue(6) :476-479.DOI:10.19908/j.cnki.ISSN1000-1255.2024.06.0476

热法聚合丁腈橡胶40 H与3604结构和性能对比

Comparison of structure and properties of nitrile rubber 40 H and 3604 by hot polymerization

徐斌 张海毅 范永将 李冬红 崔国锋 刘强 高卫光
合成橡胶工业2024,Vol.47Issue(6) :476-479.DOI:10.19908/j.cnki.ISSN1000-1255.2024.06.0476

热法聚合丁腈橡胶40 H与3604结构和性能对比

Comparison of structure and properties of nitrile rubber 40 H and 3604 by hot polymerization

徐斌 1张海毅 2范永将 3李冬红 3崔国锋 1刘强 1高卫光3
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作者信息

  • 1. 中国石油兰州石化公司橡胶运行部,兰州 730060
  • 2. 中国石油兰州石化公司规划发展部,兰州 730060
  • 3. 中国石油兰州石化公司研究院,兰州 730060
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摘要

研究了新型热法聚合丁腈橡胶(NBR)40 H生胶分子结构和玻璃化转变温度、混炼胶门尼黏度和硫化特性、硫化胶耐热氧老化性能和耐油性能,并与传统热法聚合产品NBR 3604进行了对比.结果表明,NBR 40 H的分子结构与NBR 3604差异不大,二者玻璃化转变温度和加工性能均相近,热氧老化和在标准参比油中浸泡后力学性能保持率相近;NBR 40 H可以替代NBR 3604.

Abstract

Molecule structure and glass transition temperature of raw rubber of the new nitrile rubber(NBR)40 H by hot polymerization,and Mooney vis-cosity and curing characteristics of the compound,as well as thermal-oxidative aging resistance and oil re-sistance of the vulcanizates,were studied and com-pared with the traditional hot polymerized product NBR 3604.The results showed that the molecule structure of NBR 40 H was not significantly different from that of NBR 3604,both had similar glass tran-sition temperatures and processing properties,and the mechanical property retention rates after ther-mal-oxidative aging and immersed in standard refe-rence oil were also similar.NBR 40 H could replace NBR 3604.

关键词

热法聚合/丁腈橡胶/分子结构/标准参比油/耐热氧老化性能/耐油性能

Key words

hot polymerization/nitrile rubber/molecule structure/standard reference oil/thermal-oxidative aging resistance/oil resistance

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出版年

2024
合成橡胶工业
中国石油天然气股份有限公司兰州石化分公司

合成橡胶工业

CSTPCD
影响因子:0.401
ISSN:1000-1255
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