首页|纳米银/石墨烯负载涤纶织物的制备及其结构与性能研究

纳米银/石墨烯负载涤纶织物的制备及其结构与性能研究

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采用浸渍烘干法在经碱减量处理后的涤纶织物表面负载氧化石墨烯(GO),再通过纳米银(Ag)自组装制备具有良好电热性能的纳米Ag/石墨烯负载涤纶织物,研究了GO水分散液浸渍次数、柠檬酸钠溶液浓度及硝酸银溶液浓度对织物电热性能的影响,并对织物的结构、热性能及力学性能进行表征.结果表明:制备纳米Ag/石墨烯负载涤纶织物的较佳工艺条件为GO水分散液浸渍5 次、柠檬酸钠溶液浓度 0.1 mol/L、硝酸银溶液浓度 0.1 mol/L;在纳米Ag/石墨烯负载涤纶织物制备过程中,GO和Ag+被还原成石墨烯和纳米Ag,并在织物表面形成致密且完整的高纯度纳米Ag;纳米Ag/石墨烯负载涤纶织物与未处理涤纶织物相比,具有更好的热稳定性,断裂强力相当;在 3 V电压条件下通电 60 s时,纳米Ag/石墨烯负载涤纶织物表面发热温度达到113℃,具有优异的电热性能.
Preparation of nanosilver/graphene loaded polyester fabric and structure and properties thereof
Graphene oxide(GO)was loaded onto alkali-reduced polyester fabric surface by dipping-drying method,followed by self-assembly of silver(Ag)nanoparticles to produce a nano-Ag/graphene loaded polyester fabric with fairly good electrothermal property.The influence of the dipping times in GO aqueous dispersion,sodium citrate concentration and silver nitrate concentra-tion on the electrothermal property of the nanosilver/graphene loaded PET fabric was investigated.The structure,thermal proper-ty and mechanical properties of the fabric were characterized.The results showed that the preparation conditions of nano-Ag/gra-phene loaded polyester fabric were optimized as follows:5 dipping cycles in GO aqueous dispersion,a sodium citrate concentra-tion of 0.1 mol/L and a silver nitrate concentration of 0.1 mol/L;GO and Ag+ were reduced to graphene and nano-Ag to form dense and complete high-purity nano-Ag on the surface of the fabric during the preparation process of nano-Ag/graphene-loaded polyester fabric;the nano-Ag/graphene loaded polyester fabric had better thermal stability,and comparable breaking strength as compared with the original polyester fabric;and the surface heating temperature of the nano-Ag/graphene loaded polyester fabric reached 113℃when subjected to a voltage of 3 V for 60 s,showing excellent electrothermal properties.

polyester fabricnanosilvergraphenedipping-drying methodelectrothermal property

蔡忠波、张乾、林煜尧

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宁波市产品食品质量检验研究院(宁波市纤维检验所),浙江 宁波 315048

南通大学 纺织服装学院,江苏 南通 226019

涤纶织物 纳米银 石墨烯 浸渍烘干法 电热性能

2024

合成纤维工业
中国石化集团巴陵石油化工有限责任公司 中国石化集团公司合成纤维科技情报中心站

合成纤维工业

CSTPCD
影响因子:0.417
ISSN:1001-0041
年,卷(期):2024.47(2)
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