合成纤维工业2024,Vol.47Issue(3) :33-41.

市售生物可降解塑料袋的降解行为研究

Study on degradation behavior of commercially available biodegradable plastic bags

李莹 赵华珍 易春旺
合成纤维工业2024,Vol.47Issue(3) :33-41.

市售生物可降解塑料袋的降解行为研究

Study on degradation behavior of commercially available biodegradable plastic bags

李莹 1赵华珍 1易春旺1
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作者信息

  • 1. 湖南师范大学 化学化工学院,湖南 长沙 410081
  • 折叠

摘要

选择市场上使用最广泛的由纯聚对苯二甲酸己二酸丁二酯(PBAT)、淀粉(St)质量分数 20%和30%的PBAT/聚乳酸(PLA)/St制备的生物可降解塑料袋为研究对象,分别考察了几种塑料袋在空气、水、酸碱溶液,以及自然土壤和有机土壤中的长期降解行为.结果表明:由纯PBAT和PBAT/PLA/St制备的生物可降解塑料袋在空气、水、酸碱溶液,以及自然土壤和有机土壤中经历 54 周的降解后力学性能下降较快,但仍具有较高的相对分子质量,并未呈现预期的优异生物可降解性;碱性环境相对于酸性环境更有利于生物可降解塑料袋的碎裂和降解;生物可降解塑料袋中组分St含量越高,相同降解周期下塑料袋出现的孔洞越多,相对分子质量下降越多;由纯PBAT制备的生物可降解塑料袋在酸性环境下有利于细菌的生长,但对降解作用有限.

Abstract

The most widely used poly(butylene adipate-co-terephthalate)(PBAT)/polylactic acid(PLA)/starch(St)biode-gradable plastic bags in the market with the mass fractions of PBAT and St of 20%and 30%,respectively,were selected as the research objects to investigate their long-term degradation behavior in air,water,acid-base solutions,natural soil and organic soil.The results showed that the biodegradable plastic bags prepared from pure PBAT and PBAT/PLA/St showed a rapid de-crease in mechanical properties after 54 weeks of degradation in air,water,acid-base solutions,natural soil,and organic soil,but still had high relative molecular mass and did not exhibit the expected excellent biodegradability;alkaline environments were more conducive to the fragmentation and degradation of biodegradable plastic bags as compared to acidic environments;the higher the content of St component was in biodegradable plastic bags,the more pores appeared in the plastic bags under the same degra-dation cycles and the greater the relative molecular mass decreased;and biodegradable plastic bags prepared from pure PBAT were beneficial to bacterial growth in acidic environments,but their degradation effect was limited.

关键词

生物可降解塑料袋/聚对苯二甲酸己二酸丁二酯/淀粉/聚乳酸/降解行为

Key words

biodegradable plastic bag/poly(butylene adipate-co-terephthalate)/starch/polylactic acid/degradation behavior

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出版年

2024
合成纤维工业
中国石化集团巴陵石油化工有限责任公司 中国石化集团公司合成纤维科技情报中心站

合成纤维工业

CSTPCD
影响因子:0.417
ISSN:1001-0041
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