首页|PET/rGO/SWCNT复合织物的制备及其电磁屏蔽性能研究

PET/rGO/SWCNT复合织物的制备及其电磁屏蔽性能研究

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利用氧化石墨烯(GO)优异的分散能力实现单壁碳纳米管(SWCNT)在溶液中的均匀分散,成功制备GO/SWCNT均匀混合涂覆液;通过简单可扩展的浸涂方法将GO/SWC-NT 混合液成功涂覆于聚对苯二甲酸乙二醇酯(PET)织物表面,随后通过低温热还原处理,制备了具有高导电性的PET/rGO/SWCNT电磁屏蔽复合织物.结果表明:GO表面的含氧基团可与亲水处理的PET之间形成氢键,增强界面间相互作用力;GO/SWCNT的负载量随着浸涂次数的增加而增加,经过10次浸涂循环和热还原后,最终复合织物中rGO/SWCNT的单位面积负载量为2.7 mg/cm2;制备的PET/rGO/SWCNT复合织物具有连续而致密的导电网络,电导率可达41.6 S/m,X波段平均电磁干扰屏蔽效能为22 dB;柔性PET/rGO/SWCNT复合织物不仅易于加工,而且表现出优异的导电性和电磁干扰屏蔽效能,在电磁屏蔽织物的应用中展现出巨大的潜力.
Preparation and electromagnetic shielding properties of PET/rGO/SWCNT composite fabric
Graph ene oxide(GO)with excellent dispersion ability can assist the dispersion of single-walled carbon nanotube(SWCNT)and promote the formation of uniform and stable GO/SWCNT coating liquid.The highly conductive polyethylene terephthalate/reduced graphene oxide/SWCNT(PET/rGO/SWCNT)electromagnetic shielding composite fabric was success-fully prepared by anchoring rGO/SWCNT on PET fabric via dip-coating piror to low-temperature thermal reduction.The results showed that the carboxyl groups and hydroxyl groups formed of hydrophilic-treated PET were conducive to the formation of hy-drogen bonds with that of GO,which enhanced the interaction between PET fabric and GO/SWCNT coating;the loading of GO/SWCNT increased with the number of dip-coating,the unit area loading of rGO/SWCNT in the final composite fabric was 2.7 mg/cm2 after 10 dip-coating cycles and thermal reduction;the PET/rGO/SWCNT composite fabric had a continuous and dense conductive network,with a conductivity of up to 41.6 S/m and the average electromagnetic interference shielding effec-tiveness in X-band was 22 dB;the flexible PET/rGO/SWCNT composite fabric was not only easy to process,but also exhibited excellent conductivity and shielding efficiency,showing great potential in the application of electromagnetic shielding fabrics.

electromagnetic interference shieldinggraphene oxidesingle-walled carbon nanotubesconductive fabricthermal reduction

张旭、刘雪姣、闫业海

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青岛科技大学高分子科学与工程学院,山东青岛 266042

电磁屏蔽 氧化石墨烯 单壁碳纳米管 导电织物 热还原

2024

合成纤维工业
中国石化集团巴陵石油化工有限责任公司 中国石化集团公司合成纤维科技情报中心站

合成纤维工业

CSTPCD
影响因子:0.417
ISSN:1001-0041
年,卷(期):2024.47(5)
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