首页|纳米SiOx掺杂对LDPE击穿强度的影响

纳米SiOx掺杂对LDPE击穿强度的影响

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采用傅立叶红外光谱对添加有纳米SiOx粒子的LDPE微观结构进行了分析:复合材料中的纳米SiOx的谱峰波数变小,聚乙烯谱峰变宽.采用直流高压发生器对复合材料的击穿强度进行了测量,其击穿强度相对于纯聚乙烯大,并随着纳米SiOx粒子浓度的增加,先增加后减小.这是由于纳米SiOx粒子表面的强吸附能力,在LDPE分子链之间形成了类似于“交联点”,增加了分子链之间的作用力,使材料的结构更加紧密,从而提高了复合材料的击穿强度.但是,当纳米粒子浓度增加到一定程度时,纳米粒子在混合过程中发生了团聚,其吸附力下降,复合材料的缺陷随着纳米SiOx粒子的添加而增加,导致材料的击穿强度随之下降.
Effects of Nano-SiOx Particles on LDPE Breakdown Strength
The microstructure between molecular of LDPE and inorganic nano-SiOx particles are analyzed by FTIR,and it is shown that the nano-SiOx wave number of apices becomes smaller,and the LDPE apices become wider.The breakdown strength of pure LDPE and nanocomposite are also measured by DC high voltage generator.From analyzing the test data,it can be seen that the breakdown strength of nanocomposite is higher than that of pure LDPE,and first increases then decreases with the nano-SiOx particles content increasing.The reason is that the addition of nanoSiOx particles to LDPE makes the structure of composite tighter because it acts as a cross point in composite,and makes the reaction between LDPE molecular stronger.Moreover,because the defects in composite become more and more serious with the content of nano-SiOx increasing,the breakdown strength of composite weakens gradually.

breakdown strengthFTIRlow-density polyethylenenano-SiOx

陈炯、戴旭益、项佩中

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上海电力学院,上海200090

国网上海市电力公司市区供电公司,上海200080

击穿场强 红外光谱 低密度聚乙烯 纳米SiOx

2014

华东电力
华东电力试验研究院有限公司

华东电力

CSTPCD
影响因子:0.551
ISSN:1001-9529
年,卷(期):2014.42(8)
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