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蒸汽发生器沉积物在EDTA溶液中溶解行为

Dissolution Behavior of Steam Generator Deposit in EDTA Solution

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为了研究化学清洗剂乙二胺四乙酸(EDTA)对模拟沉积物Fe3O4和蒸汽发生器(SG)泥渣的溶解能力,以指导化学清洗工艺选择,采用X射线荧光光谱和电感耦合等离子体发射光谱分析温度、EDTA浓度、溶解时间对模拟沉积物Fe3O4和SG泥渣的溶解效果.采用Fe3O4制备化学修饰电极,采用三电极体系开展修饰电极的循环伏安测试和交流阻抗测试.结果表明,溶液温度越高,EDTA浓度越高,对Fe3O4的溶解能力越强;溶解时间越长,模拟沉积物Fe3O4和SG泥渣的溶解率越高;由于SG泥渣和模拟沉积物Fe3O4的差异性,EDTA溶液对SG泥渣的溶解能力弱于模拟沉积物Fe3O4;修饰电极在EDTA溶液中的电化学反应过程属于扩散控制过程.
In order to explore the solubility of chemical cleaning agent EDTA on simulated deposit Fe3O4 and steam generator sludge,and to guide the selection of chemical cleaning processes,XRF and ICP-OES were used to analyze the dissolution effects of solution temperature,EDTA concentration,and dissolution time on simulated deposit Fe3O4 and SG sludge.The chemically modified electrode was prepared by Fe3O4,and the cyclic voltammetry test and AC impedance test of the modified electrode were carried out by using a three-electrode system.The results indicate that the higher the solution temperature,the higher the EDTA concentration,and the stronger the solubility of Fe3O4.The longer the dissolution time,the higher the dissolution rate of Fe3O4 and SG sludge.Due to the differences between SG sludge and Fe3O4,EDTA solution has a weaker ability to dissolve SG sludge than Fe3O4.The electrochemical reaction process of Fe3O4 modified electrode in EDTA solution is diffusion-controlled process.

Steam generator(SG)Fe3O4SludgeChemically modified electrodeEDTA

宋利君、肖艳、孙云、田朝晖、刘灿帅、邹伟

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苏州热工研究院有限公司,江苏苏州,215004

国家核电厂安全及可靠性工程技术研究中心,江苏苏州,215004

蒸汽发生器(SG) Fe3O4 泥渣 化学修饰电极 乙二胺四乙酸(EDTA)

2024

核动力工程
中国核动力研究设计院

核动力工程

CSTPCD北大核心
影响因子:0.3
ISSN:0258-0926
年,卷(期):2024.45(4)