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煤层气制乙炔流程模拟与分析

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为缓解电石法制乙炔中高污染、高能耗的现状、推广甲烷部分氧化法工艺,同时改善国内煤层气(Coal-Bed Methane,CBM)利用率,本文搭建了一套以煤层气为原料且采用部分氧化法生产乙炔的工艺模型.结合乙醇胺(MEA)脱碳工艺吸收CO2,利用Aspen Plus软件完成了煤层气制乙炔的全流程模拟,并进行了技术经济和环境影响分析.结果表明:本工艺年产乙炔 3×104 t(纯度大于 99%),乙炔成本为 12 423.73 CNY/t,还可以副产 1.86×104 t氢气(纯度99.99%),具备良好的综合经济效益;本工艺每生产1t乙炔排放3 048.66 kg CO2,仅为主流电石法碳排放量(6 560 kg)的46.5%,碳减排优势突出.
Process Simulation and Analysis of Acetylene Production from Coal-Bed Methane
In order to alleviate the high pollution and high energy consumption of the calcium carbide method for acetylene production,and to promote the partial oxidation of methane process,while improving the utilization rate of domestic coal-bed methane(CBM),this paper proposes a process for producing acetylene using partial oxidation of CBM as a raw material.This process is combined with the ethanolamine(MEA)CO2 absorption process,and the model is built using Aspen Plus software.Full simulation,including sensitivity analysis,economic analysis,and carbon emission analysis of the process is performed.The results show that this process can meet an annual production of 3×104 t of acetylene with a purity greater than 99%,and the cost of acetylene is 12423.73 CNY/t.It can also produce 1.86×104 t/a of hydrogen with a purity of 99.99%,demonstrating good overall economic benefits.The carbon emission analysis shows that this process emits 3048.66 kg of CO2 per ton of acetylene produced,which is only 46.5%of 6560 kg produced by the mainstream calcium carbide method.

coal-bed methaneacetylenepartial oxidationeconomic analysiscarbon emission

彭云飞、张桥

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西安交通大学化学工程与技术学院,西安 710049

乙炔 煤层气 部分氧化法 经济分析 碳排放

2024

华东理工大学学报(自然科学版)
华东理工大学

华东理工大学学报(自然科学版)

CHSSCD北大核心
影响因子:0.289
ISSN:1006-3080
年,卷(期):2024.50(4)