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洛河洛阳段沉积物重金属空间分布及潜在生态风险

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为明晰洛河洛阳段沉积物重金属分布、风险及来源,以洛河洛阳段为研究对象,采集入城区段、主城区段和出城区段13个点位的表层沉积物,分析重金属(Pb、Cd、Cr、Mo、Cu和Zn)的空间分特征,并利用地累积指数(Igeo)法、潜在生态风险指数(RI)法和主成分分析等方法评价重金属污染程度、潜在生态风险及来源解析,结果显示:洛河洛阳段沉积物重金属平均质量分数Pb(42。90 mg·kg-1)、Cd(2。41 mg·kg-1)、Cr(76。86 mg·kg-1)、Mo(9。31 mg·kg-1)、Cu(35。15 mg·kg-1)及Zn(145。60 mg·kg-1)分别为黄河流域河南段重金属元素土壤背景值的1。7、14。2、1。1、13。7、1。5和2。2倍。Pb、Cr和Cu质量分数均表现为入城区段显著高于出城区段,Cd、Mo和Zn表现为主城区段显著高于出城区段,这6种重金属质量分数在入城区段与主城区段间无显著差异。入城区段和主城区段多数点位的Cd为偏重污染程度及以上,Mo为中度污染或偏重污染程度,其余为轻度或低污染程度。源解析显示,Pb、Cd、Mo、Cu和Zn主要为人为源,Cr以自然源为主。潜在生态风险指数法结果显示,入城区点位达到强生态危害水平(Ⅲ级)及以上,主城区段所有点位均达到很强生态危害水平(Ⅳ级),出城区段所有点位均达到强生态危害水平(Ⅲ级),其中,Cd对RI的贡献最大,占比64。10%,其次是Mo(32。67%)。洛阳市应重点关注由钼产业可能引起的环境风险,并进一步降低Cd污染水平,方能降低洛河沉积物重金属的污染及潜在生态风险。
Spatial distribution and ecological risk of heavy metals in the sediments of the Luoyang section of the Luohe River
In order to clarify the distribution,risks,and sources of heavy metals in the sediments of the Luoyang section of the Luohe River,surface sediments were collected from 13 sites located in the upstream urban area,the main urban area,and the downstream urban area.Spatial distribution characteristics of heavy metals(Pb,Cd,Cr,Mo,Cu,and Zn)were ana-lyzed.The geoaccumulation index(Igeo),potential ecological risk index(RI),and principal component analysis were used to evaluate the pollution level,potential ecological risks,and identify the sources of heavy metals.The results showed that the av-erage mass fraction of heavy metal in the sediments,Pb(42.90 mg·kg-1),Cd(2.41 mg·kg-1),Cr(76.86 mg·kg-1),Mo(9.31 mg·kg-1),Cu(35.15 mg·kg-1)and Zn(145.60 mg·kg-1)were 1.7,14.2,1.1,13.7,1.5,and 2.2 times of the soil background values of heavy metals in Henan section of the Yellow River Basin,respectively.The contents of Pb,Cr and Cu in sediments in the upstream urban area were significantly higher than those in the downstream urban area,the contents of Cd,Mo,and Zn in the main urban area were significantly higher than those in the downstream urban area.There was no signif-icant difference between the upstream urban area and the main urban area.In the upstream urban area and the main urban area,the Cd pollution level at most sites reaches moderate to severe,while Mo pollution is moderate to severe,and the rest are mild or low.Source analysis indicates that Pb,Cd,Mo,Cu,and Zn mainly originate from anthropogenic sources,while Cr is primarily a natural source.The RI results showed that the sites in the upstream urban area have reached a strong ecological hazard level(Grade Ⅲ)or above,all sites in the main urban area have reached a very strong ecological risk level(Grade Ⅳ),while all sites in the downstream urban area were at a strong ecological risk level(Grade Ⅲ).Among them,Cd contributes the most(64.10%)to the RI,followed by Mo(32.67%).Luoyang City should focus on environmental risks potentially caused by the molybdenum industry and further reduce Cd pollution levels to mitigate heavy metal pollution and potential ecological risks in the Luohe River sediments.

Luohe RiverLuoyang sectionsedimentheavy metalpotential ecological risk

刘德鸿、石兆勇

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河南科技大学 农学院,河南洛阳 471000

洛河 洛阳段 沉积物 重金属 潜在生态风险

2025

河南师范大学学报(自然科学版)
河南师范大学

河南师范大学学报(自然科学版)

北大核心
影响因子:0.285
ISSN:1000-2367
年,卷(期):2025.53(1)