合肥工业大学学报(自然科学版)2024,Vol.47Issue(10) :1427-1433.DOI:10.3969/j.issn.1003-5060.2024.10.020

水下不分散混凝土抗分散剂优化设计与凝结时间调控

Optimization design of anti-dispersant and setting time regulation for non-dispersible underwater concrete

刘祥胜 纪厚祥 郑圣飚 詹炳根 余其俊 李占甫
合肥工业大学学报(自然科学版)2024,Vol.47Issue(10) :1427-1433.DOI:10.3969/j.issn.1003-5060.2024.10.020

水下不分散混凝土抗分散剂优化设计与凝结时间调控

Optimization design of anti-dispersant and setting time regulation for non-dispersible underwater concrete

刘祥胜 1纪厚祥 1郑圣飚 2詹炳根 3余其俊 3李占甫4
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作者信息

  • 1. 安徽省交通控股集团有限公司,安徽 合肥 230088
  • 2. 合肥工业大学土木与水利工程学院,安徽 合肥 230009
  • 3. 合肥工业大学土木与水利工程学院,安徽 合肥 230009;水泥基材料低碳技术与装备教育部工程研究中心,安徽 合肥 230009;安徽省水泥基材料低碳技术工程研究中心,安徽 合肥 230009
  • 4. 中交二航局第四工程有限公司,安徽芜湖 241000
  • 折叠

摘要

水下不分散混凝土(non-dispersible underwater concrete,NDC)为涉水工程的施工提供抗冲刷能力,为实现水下不分散混凝土性能的提升,文章探讨抗分散剂的优化设计和凝结时间的调控,选取聚丙烯酰胺(polyacrylamide,PAM)和羟丙基甲基纤维素(hydroxypropyl methyl cellulose,HPMC)作为抗分散剂主剂,聚羧酸减水剂、有机硅和聚醚类消泡剂作为辅剂,从抗分散性和流动性的角度对水下不分散混凝土抗分散剂的组成进行优化设计,同时选取碳酸锂和硫酸铝作为调凝剂,对水下不分散混凝土的凝剂时间进行调控.研究结果表明:采用HPMC作为主剂、聚羧酸减水剂和聚醚类消泡剂作为辅剂制备抗分散剂,可以使得水下不分散混凝土具有较好的抗分散性和流动性;其中,含水泥质量分数0.45%的HPMC和1%聚羧酸减水剂的新拌水泥砂浆(水胶质量比为0.5,胶砂质量比为2)表现出优异的抗分散性和良好的流动性,其pH值为9,扩展度为150 mm;在该体系中,硫酸铝的调凝效果较好且经济效益更高,但使用时用量应少于2%.对抗分散剂的优化设计和凝结时间的调控为水下不分散混凝土的相关实验研究提供了重要参考.

Abstract

Non-dispersible underwater concrete(NDC)provides erosion resistance for the construction of wading projects.In order to improve the performance of NDC,the optimization design of anti-dis-persant and the regulation of setting time were investigated.Polyacrylamide(PAM)and hydroxyprop-yl methyl cellulose(HPM C)were selected as the main anti-dispersants,and polycarboxylic acid water-reducing agent,silicone and polyether defoamer were selected as the auxiliary agents to optimize the design of NDC anti-dispersant from the perspective of anti-dispersion and flowability.Lithium carbon-ate and aluminum sulfate were selected as setting agents to regulate the setting time of NDC.The re-sults show that the NDC anti-dispersant,which was prepared with HPMC as the main agent,polycar-boxylic acid water-reducing agent and polyether defoamer as auxiliary agents,displays superior anti-dispersion and flowability.The fresh cement mortar(water-to-cement mass ratio is 0.5 and cement-to-sand mass ratio is 2)containing 0.45%HPMC and 1%poly carboxylic acid water-reducing agent by mass of cement shows excellent anti-dispersion and good flowability with a pH value of 9 and an ex-tension of 150 mm.In this system,aluminum sulfate is more effective and economical in regulating the setting time,but the dosage should be less than 2%.This paper provides reference for experimen-tal research related to NDC by optimizing the design of anti-dispersant and regulating the setting time.

关键词

水下不分散混凝土(NDC)/抗分散剂/减水剂/凝结时间

Key words

non-dispersible underwater concrete(NDC)/anti-dispersant/water-reducing agent/setting time

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基金项目

国家自然科学基金资助项目(51972115)

合肥工业大学产学研校企合作资助项目(W2020JSKF0615)

出版年

2024
合肥工业大学学报(自然科学版)
合肥工业大学

合肥工业大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.608
ISSN:1003-5060
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