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不同脱灰助剂对DCC装置油浆脱灰效果的研究

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某石化公司催化裂解(DCC)装置外甩油浆的灰分含量为 0.2%~0.3%,在输送管路中加入油浆脱灰助剂(比例为 300 mg/kg),在油浆储罐中静态沉降 72 h(温度为 100~105℃),要求处理后的油浆灰分含量低于 0.1%,且硅+铝含量≤60 mg/kg,以用于调配低硫船用燃料油.原用油浆脱灰助剂A以及现用油浆脱灰助剂B,脱除率均可满足技术指标.因清理库存需要,拟将之前剩余的油浆脱灰助剂A用于装置中,但对两种药剂混用是否会影响脱灰效果尚不清楚.针对此问题,开展了试验研究,结果表明不同油浆脱灰助剂混合后会出现浑浊、分层和析出胶状物的现象,脱灰效果介于两者之间.
Study on the Effect of Different Deashing Agents on the Slurry Deashing of DCC Unit
The ash content of the slurry oil rejected from the catalytic cracking(DCC)unit of a petrochemical company is 0.2%-0.3%.Add slurry oil deashing agents(at a ratio of 300 mg/kg)to the delivery pipeline,and allow the slurry oil to settle statically in the storage tank for 72 hours(at a temperature of 100-105℃).The ash content of the treated slurry oil is required to be less than 0.1%and the silicon + aluminum content is≤60 mg/kg,for use in blending low-sulfur marine fuel oil.The removal rate of both the original slurry oil deashing agent A and the current slurry oil deashing agent B can meet the technical specifications.Due to the need to clean inventory,it is proposed to use the previously remaining oil slurry deashing agent A in the plant,but it is unclear whether mixing the two agents will affect the deashing effect.To address this issue,experimental research has been conducted,and the results show that the mixing of different slurry deashing agents can lead to turbidity,stratification and the precipitation of colloidal substances,with the deashing effect being somewhere between the two.

catalytic crackingoil slurrydeashing agentsettlement

李贵、李维

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中海石油宁波大榭石化有限公司,浙江 宁波 315812

催化裂解 油浆 脱灰助剂 沉降

2024

化工管理
中国化工企业管理协会

化工管理

影响因子:0.336
ISSN:1008-4800
年,卷(期):2024.(3)
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