首页|棉秆、核桃壳活性炭吸附SO2的性能研究

棉秆、核桃壳活性炭吸附SO2的性能研究

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以新疆棉秆、核桃壳为原料,KOH为活化剂经炭化-活化制备生物质活性炭用于吸附SO2,比较相同条件下制备的棉秆和核桃壳生物质活性炭对SO2 的吸附性能.结果表明,炭化温度 400℃,炭化时间 60 min,剂料比为 1∶1,活化温度 800℃,活化时间 60 min下制备的棉秆基活性炭对SO2 的吸附效果最好,棉秆活性炭饱和吸附量为 62.887 mg/g,核桃壳生物质活性炭的饱和吸附量为 22.050 mg/g.棉秆活性炭BET分析表明比表面积为 1217.2474 m2/g,总孔容为0.6403 cm3/g;FT-IR分析有胺基、羟基等基团;XRD分析表面有石墨晶面(002)和(100)结构;SEM分析棉秆活性炭比核桃壳活性炭孔道丰富,孔隙分布均匀.
Adsorption of SO2 by Activated Carbon from Cotton Stalk and Walnut Shell
Biomass activated carbon was prepared with Xinjiang cotton stalk and walnut shell as raw materials and KOH as activator.The adsorption properties of cotton stalk and walnut shell biomass activated carbon for SO2 adsorption were compared under the same conditions.The results show that the carbonization temperature is 400℃,the carbonization time is 60 min,and the ratio of agent to material is 1∶1.The cotton stalk actirated carbon prepared at the activation temperature of 800℃and the activation time of 60 min had the best adsorption effect on SO2.The saturated adsorption capacity of cotton stalk activated carbon was 62.887 mg/g,and that of walnut shell biomass activated carbon was 22.050 mg/g.BET analysis of activated carbon showed that the specific surface area was 1217.2474 m2/g and the total pore volume was 0.6403 cm3/g.The amino groups and hydroxyl groups were detected by FT-IR analysis.XRD analysis showed that the surface of graphite crystal surface(002)and(100)structure;SEM analysis showed that the activated carbon from cotton stalk had more pores and uniform pore distribution than that from walnut shell.

cotton stalkwalnut shellbiomass activated carbonkoh methoddesulfurizationecological and environmental protection

刘媛梦、钱大益、刘焕军、李宏翰

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伊犁师范大学化学化工学院,新疆 伊宁 835000

新疆生物质清洁转化与高值化利用重点实验室,新疆 伊宁 835000

北京科技大学能源与环境工程学院,北京 100083

棉秆 核桃壳 生物质活性炭 KOH法 脱硫 生态环保

新疆维吾尔自治区自然基金

2022D01C333

2024

化工管理
中国化工企业管理协会

化工管理

影响因子:0.336
ISSN:1008-4800
年,卷(期):2024.(11)
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