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三种废渣吸附剂对稀土氨氮废水的吸附动力学研究

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以改性的粉煤灰、煤矸石、水淬渣作为材料,研究了三种废渣稀土氨氮废水中氨氮的吸附性能及其吸附动力学行为,讨论了吸附平衡时间、反应级数、吸附速率控制步骤,并将三种废渣的吸附性能进行比较.实验结果表明:粉煤灰与水淬渣较先达到吸附平衡,煤矸石与准二级动力学拟合直线的相关性最好为 0.997 8,化学反应是改性粉煤灰、改性水淬渣吸附氨氮的主要控制步骤,液膜扩散、颗粒扩散是改性煤矸石吸附氨氮的主要控制步骤.
Study on the Adsorption Kinetics of Three Types of Waste Residue Adsorbents for Rare Earth Ammonia Nitrogen Wastewater
With modified fly ash,coal gangue and water granulated slag as absorbent,the ability and kinetics of adsorption of Ammonia-Nitrogen in rare earth waster water by such 3 waste residue are studied,involving discussions on adsorption equilibrium time,reaction orders,adsorption rate control steps and effective diffusion coefficient,and the adsorption ability of the 3 waste residue are compared.The results showed:fly ash and water granulated slag reach adsorption equilibrium faster;coal gangue results has best correlation 0.9978 with quasi secondary kinetics fitting straight line;chemical reaction is the control step for adsorption of fly ash and water granulated slag,liquid film diffusion and partical diffusion are control steps for coal gangue adsorption.

waste residueadsorbentrare earth ammonia-nitrogen waste waterkinetics

杜明展、刘进峰、陈莉荣

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行唐县市同乡人民政府,河北 石家庄 050000

石家庄学院 机电学院,河北 石家庄 050035

内蒙古科技大学 能源与环境学院,内蒙古 包头 014010

废渣 吸附剂 稀土氨氮废水 动力学

2024

化工管理
中国化工企业管理协会

化工管理

影响因子:0.336
ISSN:1008-4800
年,卷(期):2024.(16)
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