化工管理2024,Issue(20) :53-55.DOI:10.19900/j.cnki.ISSN1008-4800.2024.20.014

石墨炉原子吸收法测定工作场所空气中钒条件的优化

Optimization of Vanadium in Workplace Air by Graphite Furnace Atomic Absorption Spectrometry

吴尧 杨皓越 周洋 宋亚玲
化工管理2024,Issue(20) :53-55.DOI:10.19900/j.cnki.ISSN1008-4800.2024.20.014

石墨炉原子吸收法测定工作场所空气中钒条件的优化

Optimization of Vanadium in Workplace Air by Graphite Furnace Atomic Absorption Spectrometry

吴尧 1杨皓越 1周洋 1宋亚玲1
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作者信息

  • 1. 重庆惠能标普科技有限公司,重庆 401121
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摘要

通过选择消解液、基体改进剂以及灰化、原子化温度,确定石墨炉原子吸收法测定工作场所空气中钒的测定条件,并用加标回收率和精密度进行验证.优化后钒的检测范围为 0~100 μg/L,检出限为 2 μg/L,最低检出浓度为 0.000 3 mg/m3,相对标准偏差为 0.70%~1.14%,加标回收率为 96.4%~103.9%.结果表明条件优化后的石墨炉原子吸收光谱法可快速、准确地测定工作场所空气中钒及其化合物.

Abstract

The determination conditions of vanadium in workplace air by graphite furnace atomic absorption method were determined by selecting digestion solution,matrix modifier and ashing and atomization temperature,and verified by standard recovery and precision.After the optimization,the detection range of vanadium was 0~100 μg/L,the detection limit was 2 μg/L,the minimum detection concentration was 0.000 3 mg/m3,the relative standard deviation was 0.70%~1.14%,and the recovery rate was 96.4%~103.9%.The results show that the optimized graphite furnace atomic absorption spectrometry can determine vanadium and its compounds in workplace air quickly and accurately.

关键词

/石墨炉原子吸收法/工作场所空气/条件优化

Key words

vanadium/graphite furnace atomic absorption method/workplace air/condition optimization

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出版年

2024
化工管理
中国化工企业管理协会

化工管理

影响因子:0.336
ISSN:1008-4800
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