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基于合成化工的ARM固态锂电池电解质开发及电化学性能分析

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文章采用一种化学工程合成方法开发了丙烯酸酯无规共聚物(ARM)新型化工固态锂电池电解质.通过添加无机填料(如A2O3、SiO2)并优化电解质的制备工艺,成功提高了电解质的离子电导率和电化学性能.实验结果显示,ARM基电解质在室温下的离子电导率达 3.2×10-4 S/cm,且具有较低的活化能和良好的锂离子迁移数.该电解质在NCM811|Li全电池中表现出优异的循环稳定性和倍率性能,展现出在高安全性、高能量密度固态锂电池中的应用潜力.
Development and Electrochemical Performance Analysis of Arm Solid-state Lithium Battery Electrolyte Based on Synthetic Chemistry
This paper presents a novel chemical engineering synthesis method for developing an acrylic acid ester random copolymer(ARM)as a new type of solid-state lithium battery electrolyte.By adding inorganic fillers(such as A2O3 and SiO2)and optimizing the preparation process of the electrolyte,the ionic conductivity and electrochemical performance of the electrolyte were successfully improved.Experimental results show that the ARM-based electrolyte has an ionic conductivity of 3.2×10-4 S/cm at room temperature,with a lower activation energy and good lithium ion transference number.This electrolyte exhibits excellent cycle stability and rate performance in NCM811|Li full cells,demonstrating its potential for application in high-safety,high-energy-density solid-state lithium batteries.

solid-state lithium batteriesacrylic acid ester random copolymerionic conductivitychemical synthesis

牛鹏丽

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宁德时代新能源科技股份有限公司,福建 宁德 352100

固态锂电池 丙烯酸酯无规共聚物 离子电导率 合成化工

2024

化工管理
中国化工企业管理协会

化工管理

影响因子:0.336
ISSN:1008-4800
年,卷(期):2024.(35)