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影响碳四烯烃转化装置反应器催化剂寿命因素探究

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碳四烯烃转化装置是利用乙烯和不饱和碳四发生歧化反应制丙烯的生产装置,装置的主反应设备为反应器,文章以某厂实际运行装置数据为基础,研究影响反应器催化剂使用寿命的物理因素、化学因素及正常使用过程中的损耗因素,逐一分析各种末端原因。研究结果表明,催化剂的寿命主要受充泄压速率过快、联锁排火炬泄压以及反应温度过高三个因素影响。根据以上因素制定不同的优化措施,通过优化反应温度可将催化剂寿命延长1倍,通过增加充泄压小旁路及优化联锁逻辑,可大幅减少催化剂的物理损坏,催化剂寿命可由设计的2年提升至6年。
Exploration of Factors Influencing the Lifetime of Catalysts in C4 Olefin Conversion Unit Reactors
The C4 olefin conversion unit is a production unit that uses ethylene and unsaturated C4 to undergo disproportionation reaction to produce propylene.The main reaction equipment of the unit is the reactor.Based on the actual operating data of a certain factory,this paper studies the physical and chemical factors that affect the service life of the reactor catalyst,as well as the loss factors during normal use.Various end causes are analyzed one by one.The research results show that the service life of the catalyst is mainly affected by three factors:charge and pressure relief rate too quickly,interlocking torch release pressure,and high reaction temperature.Based on the above factors,different optimization measures can be formulated.By optimizing the reaction temperature,the lifespan of the catalyst can be doubled.By add a charge and pressure relief bypass route and optimizing the interlocking logic,the physical damage to the catalyst can be greatly reduced.The lifespan of the catalyst can be increased from the designed 2 years to 6 years.

olefin conversiondisproportionation reactioncatalyst lifereaction temperature

张泽宇

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国能新疆化工有限公司,新疆乌鲁木齐 831400

烯烃转化 歧化反应 催化剂寿命 反应温度

2024

化工管理
中国化工企业管理协会

化工管理

影响因子:0.336
ISSN:1008-4800
年,卷(期):2024.(36)