首页|CeO2-In2O3异质结复合材料的制备及其在三乙胺气敏监测中的应用

CeO2-In2O3异质结复合材料的制备及其在三乙胺气敏监测中的应用

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以In(NO3)3∙4.5H2O和Ce(NO3)3∙6H2O为原料,对苯二甲酸为配体,N,N-二甲基甲酰胺为有机溶剂,通过热解金属有机骨架法(MOFs)成功制备了CeO2-In2O3复合材料.采用X射线双晶粉末衍射仪(XRD)、透射电子显微镜(TEM)、扫描电子显微镜(SEM)、紫外-可见漫反射吸收光谱(UV-vis)和比表面积与孔隙度分析仪(BET)对材料的微观结构进行表征,研究了CeO2-In2O3复合材料的气敏性能.结果表明,当In/Ce摩尔比为3∶1时,CeO2-In2O3对1×105μg/L三乙胺(TEA)的响应值(48.37)最高,是纯In2O3(9.45)的5倍,响应/恢复时间缩短至36s/22s,且该复合材料在173℃的最佳工作温度下具有优异的选择性和长期稳定性.复合材料传感性能的增强可归因于热解金属有机骨架法提供的大比表面积以及n-n异质结的形成.
Preparation of CeO2-In2O3 heterojunction composites for gas sensing monitoring of triethylamine
CeO2-In2O3 composites were synthesized by pyrolysis metal-organic framework method(MOFs)using In(NO3)3∙4.5H2O and Ce(NO3)3∙6H2O as raw materials,terephthalic acid as ligand and N,N-dimethylformamide as organic solvent.The microstructure of the obtained materials was characterized by XRD,TEM,SEM,UV-vis and BET.The gas sensitive properties of obtained CeO2-In2O3 composites were studied.The results indicated that when the molar ratio of In/Ce was 3∶1,CeO2-In2O3 to 1×105μg/L triethylamine(TEA)had the highest response values(48.37),which was 5 times that of pure In2O3(9.45),response/recovery time was reduced to 36s/22s,and the composite had excellent selectivity and long-term stability at the optimum operating temperature of 173℃.The increased sensing performance can be attributed to the large specific surface area provided by pyrolytic metal-organic skeleton method and the formation of n-n heterojunction.

CeO2-In2O3triethylaminegas sensitive performancegas sensitive mechanismheterojunction

钟彩丽、莫秋莲、孙建华、丁宁宁、廖丹葵、孙丽霞

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广西石化资源加工及过程强化技术重点实验室,广西大学化学化工学院,广西南宁 530004

CeO2-In2O3 三乙胺 气敏性能 气敏机理 异质结

国家自然科学基金国家自然科学基金广西自然科学基金

22165001520020882018GXNSFAA294001

2024

化工进展
中国化工学会,化学工业出版社

化工进展

CSTPCD北大核心
影响因子:1.062
ISSN:1000-6613
年,卷(期):2024.43(3)
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