化工进展2024,Vol.43Issue(5) :2420-2427.DOI:10.16085/j.issn.1000-6613.2023-2100

低阶煤热溶萃取物的配煤炼焦性能

Coking performance of extracts from degradative solvent extraction of low-rank coals for coal blending and coke making

刘显哲 胡振中 胡大为 李显 贺世泽 赵纯亮 夏慈良 吴波 张小勇 罗光前 姚洪
化工进展2024,Vol.43Issue(5) :2420-2427.DOI:10.16085/j.issn.1000-6613.2023-2100

低阶煤热溶萃取物的配煤炼焦性能

Coking performance of extracts from degradative solvent extraction of low-rank coals for coal blending and coke making

刘显哲 1胡振中 1胡大为 1李显 1贺世泽 2赵纯亮 3夏慈良 3吴波 4张小勇 5罗光前 1姚洪1
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作者信息

  • 1. 华中科技大学能源与动力工程学院煤燃烧国家重点实验室,湖北 武汉 430074
  • 2. 宝钢工程技术集团有限公司,上海 201999
  • 3. 上海骁齐新材料科技有限公司,上海 201799
  • 4. 山西太钢不锈钢股份有限公司焦化厂,山西太原 030003
  • 5. 安徽工业大学化学与化工学院,安徽 马鞍山 243002
  • 折叠

摘要

目前,使用黏结性添加物进行配煤炼焦,降低焦/肥煤的使用比例,是焦化行业降本增效的重要途径.国内外学者已经在实验室阶段初步证明了低阶煤热溶萃取物替代焦/肥煤炼焦的可行性,工业化应用需要开展大规模的萃取物炼焦实际验证.基于此,本文搭建了低阶煤热溶萃取装置,并与多家焦化厂展开合作,完成了萃取物替代焦/肥煤的小焦炉实验验证.结果表明:萃取物取代20%肥煤或10%焦煤时能够明显降低焦炭的灰分,保持焦炭冷热性能基本不变.并且萃取物在炼焦过程中有72%~77%的留存率,不会造成焦炭产量的明显降低.因此,本研究明确了低阶煤热溶萃取物取代焦/肥煤炼焦方案的可行性,为焦化行业的降本增效提供了新选择,并进一步推动了低阶煤热溶萃取技术的工业化进展.

Abstract

At present,the use of binder additives for coal blending to reduce the proportion of coking/fat coal is an important way to decrease the cost and enhance the efficiency of the coking industry.Domestic and international studies have already demonstrated the feasibility of the substitution of coking/fat coal for coking by extracts from degradative solvent extraction of low-rank coals in the laboratory,but there has been no actual coking validation on a large scale.Accordingly,This paper built a low-rank coal degradative solvent extraction device and cooperated with several coking plants to complete the experimental validation of extracts replacing coking/fat coal in small coke ovens.The results showed that the extracts could significantly reduce the ash content of coke and maintain the coking performances of coke basically unchanged when replacing 20%of fat coal or 10%of coking coal.Moreover,the extract had a 72%—77%retention rate in the coke,which did not result in a significant reduction in coke yield.Therefore,this study clarified the feasibility of the extracts from degradative solvent extraction of low-rank coal to replace coking/fat coal,provided a new option for cost reduction and efficiency increase in the coking industry,and further promoted the progress of industrialization of the degradative solvent extraction of low-rank coal technology.

关键词

低阶煤/碳氢化合物/热解/溶剂萃取/焦化

Key words

low-rank coal/hydrocarbons/pyrolysis/solvent extraction/coking

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基金项目

博后面上项目(2023M731180)

出版年

2024
化工进展
中国化工学会,化学工业出版社

化工进展

CSTPCD北大核心
影响因子:1.062
ISSN:1000-6613
参考文献量6
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