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耐火材料热化学反应典型应用技术发展

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高温工业的发展,与耐火材料的发展密切相关,其技术进步无一例外地都依赖于优质耐火材料的研发。耐火材料在制备及应用过程中,都和热化学反应息息相关。本文首先简要介绍了耐火材料的发展历程,其次以二氧化硅质、莫来石质耐火材料为例,介绍了上述耐火材料制备中的热化学反应过程;以莫来石-碳化硅、方镁石-尖晶石、镁碳质耐火材料为例,介绍了上述耐火材料在服役过程中的热化学侵蚀反应行为,并给出了热化学模拟在耐火材料与熔渣/气相反应中的应用情况;以氧化铝-碳质过滤器为例,介绍了其应用过程中的吸附夹杂机理。最后介绍了常用的耐火材料煅烧设备。
Typical applications of thermochemical reactions in refractory
The development of high-temperature industry is closely related to the development of refractory materials,and the technological progress without exception depends on the research and development of high quality refractories.In the process of preparation and application,refractories are closely related to thermochemical reactions.This paper first briefly reduces the development of refractory,and secondly taking silica brick,synthetic mullite as examples,the thermochemical reactions in the preparation of these refractories are introduced.The thermochemical corrosion reactions of mullite-SiC brick,magnesia-spinel brick and magnesia-carbon brick in service is introduced,and the application of thermochemical simulation in the reactions between refractories and slag/gas is introduced.Taking alumina-carbon filter as an example,the adsorption mechanism of inclusion in its application process is introduced.Finally,the common calcining equipments for refractory are introduced.

refractorythermal chemical reactioncorrosionphase diagramsimulationcalcining equipments

李亚伟、韩兵强、鄢文、黄奥、刘浩、朱天彬、廖宁、陈俊峰、徐义彪

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武汉科技大学,省部共建耐火材料与冶金国家重点实验室,湖北武汉 430081

武汉科技大学,钢铁工业耐火材料新技术国际合作联合实验室,湖北武汉 430081

耐火材料 热化学反应 侵蚀 相图 模拟 煅烧设备

2024

化工进展
中国化工学会,化学工业出版社

化工进展

CSTPCD北大核心
影响因子:1.062
ISSN:1000-6613
年,卷(期):2024.43(7)