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化学镀铁镍碳纤维制备及其电磁屏蔽性能

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为提高碳纤维(CF)的屏蔽性能和实现宽频化应用,本文通过化学镀方法分别在CF表面沉积Ni、FeNi金属层,制备了碳纤维杂化材料(CF@Ni、CF@FeNi).其次以水性聚氨酯(WPU)为基体,依次以CF、CF@Ni和CF@FeNi为填料,制备了轻质、柔性的复合材料.同时测试了复合材料在30~3000MHz的电磁屏蔽性能和10~100kHz的磁屏蔽性能.结果表明,成功地在碳纤维表面镀覆了一层致密、均匀的金属层,其中CF@FeNi的饱和磁化强度(Ms)、剩余磁化强度(Br)和矫顽力(He)分别达到了 10.02emu/g、0.76emu/g和26.06Oe.金属镀层改善了碳纤维的电磁屏蔽性能,并有效提高了其在低频段的磁屏蔽性能.当添加量为9%时,WPU@CF@FeNi在30~3000MHz与10~100kHz的屏蔽效能峰值分别达到26.9dB和18.0dB.
Preparation and electromagnetic interference shielding properties of electroless iron-nickel plated carbon fiber
In order to improve the shielding performance of carbon fiber(CF)and realize wide-band application,carbon fiber hybrid materials(CF@Ni,CF@FeNi)were prepared by electroless plating on CF surface.Secondly,waterborne polyurethane(WPU)was used as matrix,and CF,CF@Ni and CF@FeNi were used as fillers in turn to prepare lightweight and flexible composites.At the same time,the electromagnetic shielding properties of the composites at 30-3000MHz and 10-100kHz were tested.The results showed that a dense and uniform metal layer was successfully deposited on the surface of carbon fiber,in which the saturation magnetization(Ms),remanent magnetization(Br)and coercivity(He)of CF@FeNi reached 10.02emu/g,0.76emu/g and 26.06Oe,respectively.Metal coating improved the electromagnetic shielding performance of carbon fiber and effectively improved its magnetic shielding performance in low frequency band.The peak shielding effectiveness of WPU@CF@FeNi at 30-3000MHz and 10-100kHz reached 26.9dB and 18.0dB,respectively when the addition of WPU@CF@FeNi was 9%.

electroless platingFeNi coated layercarbon fibersoft-magnetic propertieselectromagnetic shielding

周锐、俞科静、徐阳

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江南大学纺织科学与工程学院,江苏无锡 214000

化学镀 铁镍镀层 碳纤维 软磁性能 电磁屏蔽

国家重点研发计划国家重点研发计划

2022YFB38071002022YFB3807103

2024

化工进展
中国化工学会,化学工业出版社

化工进展

CSTPCD北大核心
影响因子:1.062
ISSN:1000-6613
年,卷(期):2024.43(7)
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