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PAN/MXene同轴纤维电极的制备及性能

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采用单片层MXene、聚甲基丙烯酸甲酯(PMMA)和聚丙烯腈(PAN)粉末为原料制备不同纺丝液,经过同轴湿法纺丝成型、高温炭化制备出一系列不同壳芯组分同轴纤维电极;分析不同壳层、芯层材料对纤维电极微观结构以及力学、电学、电化学等性能的影响规律。结果表明,当以PAN/MXene为壳层、PAN/PMMA为芯层时,可以实现电极材料力学性能与电化学性能的平衡,拉伸强度、电导率和比电容分别为可达到14。4MPa、322。7S/m和113。18F/g,经过1000次恒电流充放电测试(GCD)循环后,比电容保持率可达到95。7%。
Preparation and properties of PAN/MXene coaxial fiber electrode
A series of coaxial fiber electrode samples with different sheath and core component were prepared through wet-spinning method combined with subsequent high temperature carbonization.Single-layer MXene sheets,polymethyl methacrylate(PMMA)and polyacrylonitrile(PAN)were applied in this study for making various spinning solution.The influence of different material constitution of the sheath and core layer on the property of as-prepared fiber electrodes,including microstructure,mechanical strength,electrical conductivity and electrochemical performance,was discussed and analyzed.The results showed that the fiber electrode sample with PAN/MXene sheath layer and PAN/PMMA core layer could achieve balance between the electrochemical performance and mechanical strength.The tensile breaking strength,specific conductance and specific capacitance reached 14.4MPa,322.7S/m and 113.18F/g,respectively.In addition,the fiber electrode also had good cycle stability with capacitance retention rate at 95.7%after 1000 GCD cycles.

fiber electrodeMXenecoaxial fiberwet-spinningelectrochemical energy storage

屈芸、成丽媛、代国亮、王刚、郭羽晴、孙洁

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江南大学纺织与科学工程学院,江苏 无锡 214122

中国人民解放军军事科学院系统工程研究院,北京 100010

纤维电极 MXene 同轴纤维 湿法纺丝 电化学储能

国家自然科学基金

51903109

2024

化工进展
中国化工学会,化学工业出版社

化工进展

CSTPCD北大核心
影响因子:1.062
ISSN:1000-6613
年,卷(期):2024.43(9)