首页|纳米碳酸钙对nano-CaCO3/PES复合膜结构与性能的影响

纳米碳酸钙对nano-CaCO3/PES复合膜结构与性能的影响

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为深入了解nano-CaCO3/PES复合膜的形态结构、力学性能、亲水性、分离性能和抗污染性能,通过非溶剂诱导相分离(NIPS)技术制备了 nano-CaCO3/PES复合膜。对复合膜的形态结构和物理化学性能以及分离性能进行了表征,重点考察了 nano-CaCO3质量分数对膜结构与性能的影响。结果说明了 nano-CaCO3在膜中均匀分散时,可有效优化膜结构,并同步提升膜的物理化学性能,提高分离效率。当nano-CaCO3质量分数为0。3%时,所得到的复合膜机械强度为3。8MPa;对比纯PES材料,其机械强度增加了 65%;亲水性也有效改善,纯水渗透性为450L/(m2·h·bar)(1bar=105Pa),提高了 1。7倍,同时保持99%以上的BSA截留率;对BSA抗污性能从48。8%显著提高至77。1%,具有良好的抗污染效果。本项研究为优化膜结构、提升膜性能方面提供了一个高效、简便的方法,在实际应用中具有重要的价值。
Effect of nano-CaCO3 on structure and properties of nano-CaCO3/PES composite membrane
Nano-CaCO3/PES composite membrane was prepared by non-solvent induced phase separation(NIPS)technology to understand the morphology,mechanical properties,hydrophilicity,separation properties and anti-fouling properties of nano-CaCO3/PES composite membrane.The morphology,physical chemistry properties and separation properties of the composite membranes were characterized.The effects of nano-CaCO3 weight fraction on the structure and properties of the membranes were investigated.The results showed that nano-CaCo3 could effectively optimize the structure of the membrane,and simultaneously improve the physical chemistry performance and separation efficiency.When nano-CaCO3 weight fraction was 0.3%,the mechanical strength of the composite membrane was 3.8MPa.Compared to pure PES materials,the mechanical strength was increased by 65%.The hydrophilicity was also improved.The permeability of pure water was 450L/(m2·h·bar)(1bar=105Pa),which was increased by 1.7 times.At the same time,the retention rate of BSA was over 99%and the anti-pollution property of BSA was improved from 48.8%to 77.1%,which had good anti-pollution effect.The present study offered a highly effective and straightforward approach to optimize membrane structure and enhance membrane performance,thereby holding significant practical application value.

nano-CaCO3dispersitycomposite membranemechanical propertiesseparation performanceanti-fouling performance

王玉周、陈增、曹东鑫、周杰辉、安旭、马天琦

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河南工程学院材料工程学院,河南郑州 450000

纳米碳酸钙 分散性 复合滤膜 力学性能 分离性能 抗污染性能

2024

化工进展
中国化工学会,化学工业出版社

化工进展

CSTPCD北大核心
影响因子:1.062
ISSN:1000-6613
年,卷(期):2024.43(11)