化工进展2024,Vol.43Issue(11) :6390-6396.DOI:10.16085/j.issn.1000-6613.2023-1863

纳米氢氧化镁对无氟泡沫灭火剂性能的影响

Effect of nano-magnesium hydroxide on the performance of fluorine-free foam extinguishing agent

陈合敏 欧红香 薛洪来 闵政 曹海珍 王钧奇
化工进展2024,Vol.43Issue(11) :6390-6396.DOI:10.16085/j.issn.1000-6613.2023-1863

纳米氢氧化镁对无氟泡沫灭火剂性能的影响

Effect of nano-magnesium hydroxide on the performance of fluorine-free foam extinguishing agent

陈合敏 1欧红香 1薛洪来 1闵政 1曹海珍 1王钧奇2
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作者信息

  • 1. 常州大学安全科学与工程学院,江苏常州 213164
  • 2. 江苏锁龙消防科技股份有限公司,江苏泰州 225753
  • 折叠

摘要

以聚醚改性三硅氧烷、CTAB为表面活性剂,以纳米氢氧化镁、黄原胶为稳泡剂制备无氟泡沫灭火剂,采用L9(34)正交表分析泡沫溶液表面张力、发泡性能及稳泡性能,选用正交优化后的泡沫配方进行灭火和抗烧实验研究.研究结果表明:复配体系泡沫溶液黏度较低,在1.00~1.21mPa·s之间;由质量分数为0.8%的CTAB与12%的聚醚改性三硅氧烷组成的泡沫溶液表面张力最低,为19.73mN/m;聚醚改性三硅氧烷与CTAB协同作用,增强了溶液发泡性能与泡沫稳定性,当纳米氢氧化镁的质量分数为0.5%时,溶液的发泡高度最优,达到207mm,25%析液时间从205s增长到216s;用质量分数为1.2%CTAB、12%聚醚改性三硅氧烷、0.5%纳米氢氧化镁及0.05%黄原胶制备的泡沫灭火剂扑灭油盘面积为0.25m2的正庚烷火,灭火时间为107s,抗烧时间达到372s.

Abstract

In this paper,polyether-modified trisiloxane and CTAB as surfactants,and nano-magnesium hydroxide and xanthan gum as stabilizing agent were prepared for preparation of fluorine-free foam fire extinguishing agent.L9(34)orthogonal table was used to analyze surface tension,foaming performance and foam stability of foam solution,and orthogonally optimized foam formula was selected for fire fighting and anti-burning experimental research.The results showed that the viscosity of the compound system was low between 1.00-1.21mPa·s.The foam solution composed of CTAB with mass fraction of 0.8%and 12%polyether-modified trisiloxane had the lowest surface tension of 19.73mN/m.Polyether-modified trisiloxane cooperated with CTAB to enhance the solution foaming performance and foam stability.When the mass fraction of nanometer magnesium hydroxide was 0.5%,the solution foaming was highly optimal,reaching 207mm,and the 25%solution time increased from 205s to 216s.The foam fire extinguishing agent prepared with the mass fraction of 1.2%CTAB,12%polyether-modified trisiloxane,0.5%nano-magnesium hydroxide and 0.05%xanthan gum was used to extinguish the n-heptane fire with the oil pan area of 0.25m2,and the fire extinguishing time was 107s with the anti-burning time of 372s.

关键词

纳米氢氧化镁/表面活性剂/泡沫稳定性/灭火性能/无氟泡沫灭火剂

Key words

nano-magnesium hydroxide/surfactant/foam stability/fire extinguishing performance/fluorine-free foam extinguishing agent

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出版年

2024
化工进展
中国化工学会,化学工业出版社

化工进展

CSTPCD北大核心
影响因子:1.062
ISSN:1000-6613
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