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铕碳点对四环素的特异性识别与降解

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以柠檬酸、1.0代聚酰胺胺和氯化铕为原料,采用水热法合成了具有特异性识别四环素比例荧光探针,同时对四环素进行降解.结果表明,Eu3+-碳点(CDs)的量子产率为92%,具有抗干扰特性,可以特异性识别多种抗生素混合物中的四环素.c(四环素)=50 nmol/L~20 μmol/L,比例荧光强度和四环素浓度呈现良好线性关系,最低检测限为6 nmol/L.t=120 min,365 nm紫外光催化四环素的降解率为60%,经过5个循环的降解效率一致,具有优异的光催化稳定性.
Eu3+ carbon dots for specific recognition and degradation of tetracycline
By employing citric acid,1.0G polyamide amine,and europium chloride as starting materials,a tetracycline-specific fluorescent probe was synthesized via hydrothermal method and was used to degrade tetracycline.The obtained Eu3+-CDs exhibited a remarkable quantum yield of 92%and demonstrated excellent anti-interference properties,enabling selective recognition of tetracycline in the presence of various antibiotics.The proportional fluorescence intensity was linear with tetracycline concentration in the range of 50 nmol/L to 20 μmol/L with a detection limit of 6 nmol/L.Under 365 nm UV light for 120 mins,the degradation rate of tetracycline reached up to 60%,while maintaining consistent photocatalytic efficiency even after five consecutive cycles,thus highlighting its exceptional stability.

Eu3+ carbon dotTetracyclineSpecific recognitionPhoto catalysisDegradation

赵威轩、孟深化、施伟光

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东北石油大学化学化工学院,黑龙江大庆 163318

东北石油大学非常规油气研究院,黑龙江大庆 163318

铕碳点 四环素 特异性识别 光催化 降解

黑龙江省青年创新人才项目东北石油大学优秀科研人才培育基金

UNPYSCT-2017039SJQHB202004

2024

化工科技
中国石油天然气股份有限公司吉林石化分公司

化工科技

CSTPCD
影响因子:0.386
ISSN:1008-0511
年,卷(期):2024.32(2)