化工科技2024,Vol.32Issue(3) :35-39.

环氧树脂的亲水改性及固化特征研究

Hydrophilic modification of epoxy resin and its curing characteristics

华成武 邓刚 陈海军 宋伟强 沈超
化工科技2024,Vol.32Issue(3) :35-39.

环氧树脂的亲水改性及固化特征研究

Hydrophilic modification of epoxy resin and its curing characteristics

华成武 1邓刚 1陈海军 1宋伟强 2沈超1
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作者信息

  • 1. 河南省科学院同位素研究所有限责任公司,河南郑州 450015
  • 2. 河南工业大学,河南郑州 450001
  • 折叠

摘要

以环氧树脂E-51与二乙醇胺进行开环加成,在疏水环氧树脂分子中引入亲水基团,加酸成盐后得到环氧树脂水性体系.利用红外光谱和热失重对产物进行分析,研究了反应温度、反应时间等对反应产物的影响,最优反应温度为80 ℃,反应时间为3 h.此外,还对亲水改性环氧树脂的涂膜表干时间、附着力、硬度和柔韧性进行了研究,结果表明,亲水改性环氧树脂有良好的应用前景和价值.

Abstract

Epoxy resin E-51 and diethanolamine were selected for ring-opening addition,hydrophilic groups were introduced into hydrophobic epoxy resin molecules,and a aqueous epoxy resin system was obtained after adding acid to form salt.The products were analyzed by FT-IR and TGA.The effects of reaction temperature,reaction time,etc.on the reaction products were studied,the optimal reaction temperature was 80 ℃ and the optimal reaction time was 3 hours.The surface drying time,adhesion,hardness and flexibility of hydrophilic modified epoxy resin film were studied,and the results showed that the surface products had good application value.

关键词

环氧树脂/亲水改性/固化

Key words

Epoxy resin/Hydrophilic modification/Solidification

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基金项目

河南省科学院科研开发专项(210204016)

河南省科学院辐射新材料创新团队(20230111)

出版年

2024
化工科技
中国石油天然气股份有限公司吉林石化分公司

化工科技

CSTPCD
影响因子:0.386
ISSN:1008-0511
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