首页|环氧树脂的亲水改性及固化特征研究

环氧树脂的亲水改性及固化特征研究

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以环氧树脂E-51与二乙醇胺进行开环加成,在疏水环氧树脂分子中引入亲水基团,加酸成盐后得到环氧树脂水性体系.利用红外光谱和热失重对产物进行分析,研究了反应温度、反应时间等对反应产物的影响,最优反应温度为80 ℃,反应时间为3 h.此外,还对亲水改性环氧树脂的涂膜表干时间、附着力、硬度和柔韧性进行了研究,结果表明,亲水改性环氧树脂有良好的应用前景和价值.
Hydrophilic modification of epoxy resin and its curing characteristics
Epoxy resin E-51 and diethanolamine were selected for ring-opening addition,hydrophilic groups were introduced into hydrophobic epoxy resin molecules,and a aqueous epoxy resin system was obtained after adding acid to form salt.The products were analyzed by FT-IR and TGA.The effects of reaction temperature,reaction time,etc.on the reaction products were studied,the optimal reaction temperature was 80 ℃ and the optimal reaction time was 3 hours.The surface drying time,adhesion,hardness and flexibility of hydrophilic modified epoxy resin film were studied,and the results showed that the surface products had good application value.

Epoxy resinHydrophilic modificationSolidification

华成武、邓刚、陈海军、宋伟强、沈超

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河南省科学院同位素研究所有限责任公司,河南郑州 450015

河南工业大学,河南郑州 450001

环氧树脂 亲水改性 固化

河南省科学院科研开发专项河南省科学院辐射新材料创新团队

21020401620230111

2024

化工科技
中国石油天然气股份有限公司吉林石化分公司

化工科技

CSTPCD
影响因子:0.386
ISSN:1008-0511
年,卷(期):2024.32(3)