化工科技2024,Vol.32Issue(3) :54-60.

共价有机框架材料的制备及其对水体中刚果红的吸附性能研究

Preparation of covalent organic framework and adsorption of Congo Red in water

陆素芬 欧小玉 谢丽莎 黄柳琴 陆俊宇 王爱娟
化工科技2024,Vol.32Issue(3) :54-60.

共价有机框架材料的制备及其对水体中刚果红的吸附性能研究

Preparation of covalent organic framework and adsorption of Congo Red in water

陆素芬 1欧小玉 2谢丽莎 2黄柳琴 2陆俊宇 2王爱娟2
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作者信息

  • 1. 广西蚕桑生态学与智能化技术应用重点实验室河池学院,广西河池 546300;广西现代蚕桑丝绸协同创新中心河池学院,广西河池 546300
  • 2. 广西蚕桑生态学与智能化技术应用重点实验室河池学院,广西河池 546300
  • 折叠

摘要

为了降低水体中刚果红(CR)的污染水平,采用溶剂法在室温常压下合成了一种巯基修饰的共价有机框架材料(COFs-TFB),以不同的反应条件为考察对象进行吸附实验,研究其吸附CR的性能.通过现代化技术手段对所合成的材料进行表征.实验结果表明,COFs-TFB材料对CR的吸附速度快,适于在酸性条件下进行;COFs-TFB材料对CR的吸附表现出优先选择吸附性,且重复利用性较好;在CR初始浓度为900 mg/L时,对CR的饱和吸附量为2 124.6 mg/g;对CR的吸附过程符合准二级动力学模型和Langmuir等温吸附线模型,为单层化学吸附过程.因此,合成的COFs-TFB材料在吸附水体中刚果红领域具有良好的应用前景.

Abstract

In order to reduce the content of Congo Red(CR)in water,the covalent organic framework material(COFs-TFB)modified with sulfhydryl groups was synthesized in this experiment using a solvent method at room temperature and atmospheric pressure,and adsorption experiments were performed to study its performance in adsorption of CR with adsorption conditions as variables.The synthesized materials were characterized by modern technical means.It was found that the COFs-TFB material was suited for adsorption under acidic conditions.The COFs-TFB material exhibits preferential adsorption.The saturation adsorption amounts of 2 124.6 mg/g was reached at the initial concentrations of 900 mg/L for CR.The adsorption process of CR was in accordance with the quasi-secondary kinetic model and Langmuir adsorption isotherm model,which is a monolayer chemisorption process.In summary,the synthesized COFs-TFB materials have good adsorption performance on CR.

关键词

共价有机框架材料/刚果红/有机废水/吸附

Key words

Covalent organic framework materials/Congo Red/Organic wastewater/Adsorption

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基金项目

广西自然科学基金(2022GXNSFAA035470)

广西自然科学基金(2020GXNSFBA297138)

广西中青年能力提升项目(2024KY0630)

大学生创新创业项目(202310605010)

大学生创新创业项目(202210605031)

出版年

2024
化工科技
中国石油天然气股份有限公司吉林石化分公司

化工科技

CSTPCD
影响因子:0.386
ISSN:1008-0511
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