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金属封装型非均相沸石催化剂的研究进展

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将金属纳米颗粒固定在沸石晶体中是一种非均相催化剂(金属@沸石)的新型制备方法,在许多重要的反应中,其稳定性优于一般负载型催化剂.根据金属物种的大小及其在沸石孔道中的相对位置对金属@沸石催化剂进行分类,并简要综述了金属@沸石催化剂的合成策略及催化性能方面的研究进展,与普通负载型催化剂相比,金属@沸石催化剂具备优异的抗烧结、抗浸出性能及选择性催化性能.总结了金属@沸石催化剂面临的挑战,并对其应用前景进行展望.
Research progress in metal-encapsulated heterogeneous zeolite catalysts
Fixation of metal nanoparticles in zeolite crystals is a new preparation method for heterogeneous catalysts(metal@zeolite),which is more stable than ordinary supported catalysts in many important reactions.In this paper,metal@zeolite catalysts were classified according to the size of metal species and their relative positions in zeolite pores,and the research progress in synthesis strategy and catalytic performance of metal@zeolite catalysts were briefly reviewed.The excellent anti-sintering,anti-leaching and selective catalytic performance of metal@zeolite catalysts were emphasized compared with ordinary supported catalysts.Finally,the challenges faced by metal@zeolite catalysts were summarized,and their application prospects were prospected.

Heterogeneous catalystZeoliteNanoparticleEncapsulationCatalytic performance

陈惠莹、田宇轩、王海英、张亚男、张晓丹、刘心雨、陈彦广

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东北石油大学化学化工学院,黑龙江大庆 163318

黑龙江省石油与天然气化工省重点实验室,黑龙江大庆 163318

非均相催化剂 沸石 纳米颗粒 封装 催化性能

国家自然科学青年基金项目中国石油科技创新基金项目东北石油大学新能源新领域培育项目东北石油大学引导性创新基金项目

219080212021DQ02-0701XNYXLY2021022021YDL-03

2024

化工科技
中国石油天然气股份有限公司吉林石化分公司

化工科技

CSTPCD
影响因子:0.386
ISSN:1008-0511
年,卷(期):2024.32(4)