化工科技2024,Vol.32Issue(5) :7-10.

表面改性对溴代三嗪/Sb2O3阻燃丙烯腈-丁二烯-苯乙烯的影响

Effect of surface modification of tri(tribromophenyl)cyanurate/Sb2O3 on its flame retardancy in acrylonitrile-butadiene-styrene

杨明辉 赵婕 唐林生
化工科技2024,Vol.32Issue(5) :7-10.

表面改性对溴代三嗪/Sb2O3阻燃丙烯腈-丁二烯-苯乙烯的影响

Effect of surface modification of tri(tribromophenyl)cyanurate/Sb2O3 on its flame retardancy in acrylonitrile-butadiene-styrene

杨明辉 1赵婕 2唐林生3
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作者信息

  • 1. 寿光卫东腾冠化工有限公司,山东潍坊 262714
  • 2. 寿光卫东化工有限公司,山东潍坊 262714
  • 3. 青岛科技大学化工学院,山东青岛 266061
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摘要

通过极限氧指数(LOI)测定、垂直燃烧实验及锥形量热实验研究了溴代三嗪(TTBPC)/Sb2O3的表面改性对其阻燃丙烯腈-丁二烯-苯乙烯(ABS)的影响.结果表明,采用KH550改性TTBPC/Sb2O3 明显改善了其对 ABS 的阻燃作用,w(TTBPC/Sb2O3)=15.0%,m(TTBPC)∶m(Sb2O3)=4.0∶1.0,m(KH550)∶m(TTBPC/Sb2O3)=2.0%,改性使阻燃 ABS 的 LOI 从 25.4%提高至 29.7%、垂直燃烧等级从无提高至V-0.与纯ABS相比,阻燃ABS的总热释放量(THR)、热释放速率峰值(PHRR)和平均热释放速率(MHRR)分别降低了 58.6%、55.9%和55.0%.

Abstract

The effect of the surface modification of tri(tribromophenyl)cyanurate(TTBPC)/Sb2O3 on its flame retardancy in acrylonitrile-butadiene-styrene(ABS)was studied by limiting oxygen index(LOI)measurement,vertical combustion test and cone calorimeter test.The results show that the flame retardant effect of TTBPC/Sb2O3 in ABS is significantly improved by modification with KH550.When w(TTBPC/Sb2 O3)is 15.0%based on the total weight of the composites,m(TTBPC)∶m(Sb2O3)=4.0∶1.0,and m(KH550)∶m(TTBPC/Sb2O3)=2.0%,the LOI and vertical combustion level of flame retarded ABS increases by modification from 25.4%to 29.7%and from none to V-0,respectively.Compared pure ABS,the total heat release(THR),peak heat release rate(PHRR)and mean heat release rate(MHRR)of flame retardant ABS decreases by about 58.6%,55.9%and 55.0%,respectively.

关键词

溴代三嗪/丙烯腈-丁二烯-苯乙烯/KH550/表面改性/阻燃性能

Key words

Tri(tribromophenyl)cyanurate/Acrylonitrile-butadiene-styrene/KH550/Surface modification/Flame retardancy

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基金项目

国家自然科学基金项目(21878165)

出版年

2024
化工科技
中国石油天然气股份有限公司吉林石化分公司

化工科技

CSTPCD
影响因子:0.386
ISSN:1008-0511
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