化工科技2024,Vol.32Issue(5) :43-47.

铈掺杂ZIF-67的制备及电催化析氧性能

Preparation of cerium-doped ZIF-67 for electrocatalytic oxygen evolution performance

吕章怡 袁近秋 毕明春 梁宇宁 高彦华 陈颖
化工科技2024,Vol.32Issue(5) :43-47.

铈掺杂ZIF-67的制备及电催化析氧性能

Preparation of cerium-doped ZIF-67 for electrocatalytic oxygen evolution performance

吕章怡 1袁近秋 1毕明春 1梁宇宁 1高彦华 1陈颖1
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作者信息

  • 1. 东北石油大学化学化工学院,黑龙江大庆 163318
  • 折叠

摘要

以六水合硝酸钴、六水合硝酸铈为金属离子,2-甲基咪唑为有机配体,十六烷基三甲基溴化铵为形貌调节剂,通过一步法在水溶剂中制备掺杂不同x(Ce)的Ce-ZIF-67纳米立方体(Ce-ZIF-67 NCs).结果表明,5%Ce-ZIF-67 NCs为最佳电催化剂,电流密度为10 mA/cm2时的过电位为363 mV,电子转移电阻为178.77 Ω.Ce的掺杂具有良好的离子电导率和可逆的表面氧离子交换能力,优化Co位点的电子结构,进而提升ZIF-67 NCs的析氧性能.

Abstract

Using cobalt and cerium nitrate hexahydrate as the metal ions,2-methylimidazole as the organic ligand,and cetyltrimethylammonium bromide as the shape modifier,Ce-ZIF-67 nanocubes(Ce-ZIF-67 NCs)doped with varying Ce contents were prepared by a single step in an aqueous solvent.The results showed that 5%Ce-ZIF-67 NCs was the best electrocatalyst with an overpotential of 363 mV at a current density of 10 mA/cm2.The electron transfer resistance was 178.77 Ω.The doping of Ce has good ionic conductivity and reversible surface oxygen ion exchange ability,which optimizes the electronic structure of Co sites and thus enhances the oxygen evolution reaction performance of ZIF-67 NCs.

关键词

金属有机框架/掺杂/电催化/析氧反应

Key words

Metal-organic frameworks/Doping/Electrocatalysis/Oxygen evolution reaction

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基金项目

黑龙江省自然科学基金项目(LH2023B006)

出版年

2024
化工科技
中国石油天然气股份有限公司吉林石化分公司

化工科技

CSTPCD
影响因子:0.386
ISSN:1008-0511
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