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甲烷氯化物中微量氯单质快速分析方法研究

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为快速检测甲烷氯化物生产过程反应液中氯单质含量,以碘化钾为显色剂,将反应液中氯单质还原成氯离子,碘离子氧化成碘单质,通过目视比色法测定.通过建立标准色阶,考察显色剂用量,显色时间等对结果的影响.结果表明,该方法具有较高的准确性,加标回收率在96.8%~103.3%,检出限为1 mg/L,操作简单,可满足生产紧急需要.
Study on Rapid Analysis Method of Trace Chlorine in Methane Chloride
To quickly detect the content of chlorine element in the reaction solution of methane chloride production process,potassium iodide is used as a chromogenic agent to reduce chlorine element in the reaction solution to chloride ions,and iodine ions are oxidized to iodine element,which is determined by visual colorimetry.By establishing a standard color scale,it investigates the effects of reagent dosage,color development time,and other factors on the results.The results show that the method has high accuracy,with a spiked recovery rate of 96.8%to 103.3%,a detection limit of 1 mg/L,simple operation,and can meet urgent production needs.

methane chloridechlorinecolorimetry

陈彩琴、邵红才、吴云竹、傅永斌

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浙江衢化氟化学有限公司,浙江 衢州 324004

甲烷氯化物 氯单质 比色法

2024

化工生产与技术
巨化集团公司

化工生产与技术

影响因子:0.209
ISSN:1006-6829
年,卷(期):2024.30(2)
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